Synthesis, structure and dehydrogenation of zirconium borohydride octaammoniate
A new metal borohydride ammoniate (MBA), Zr(BH 4 ) 4 ·8NH 3 , was synthesized via ammoniation of the Zr(BH 4 ) 4 crystal. Zr(BH 4 ) 4 ·8NH 3 has a distinctive structure and the highest coordination number of NH 3 groups among all the known MBAs. This compound could quickly dehydrogenate at 130 °C, e...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2015-02, Vol.51 (14), p.2794-2797 |
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| container_title | Chemical communications (Cambridge, England) |
| container_volume | 51 |
| creator | Huang, Jianmei Tan, Yingbin Su, Jiahao Gu, Qinfen erný, Radovan Ouyang, Liuzhang Sun, Dalin Yu, Xuebin Zhu, Min |
| description | A new metal borohydride ammoniate (MBA), Zr(BH
4
)
4
·8NH
3
, was synthesized
via
ammoniation of the Zr(BH
4
)
4
crystal. Zr(BH
4
)
4
·8NH
3
has a distinctive structure and the highest coordination number of NH
3
groups among all the known MBAs. This compound could quickly dehydrogenate at 130 °C, enabling it a potential hydrogen storage material.
A novel metal borohydride ammoniate (MBA), Zr(BH
4
)
4
·8NH
3
, has a distinctive structure and the highest ammonia coordination number among all the known MBAs. |
| doi_str_mv | 10.1039/c4cc09317h |
| format | Article |
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4
)
4
·8NH
3
, was synthesized
via
ammoniation of the Zr(BH
4
)
4
crystal. Zr(BH
4
)
4
·8NH
3
has a distinctive structure and the highest coordination number of NH
3
groups among all the known MBAs. This compound could quickly dehydrogenate at 130 °C, enabling it a potential hydrogen storage material.
A novel metal borohydride ammoniate (MBA), Zr(BH
4
)
4
·8NH
3
, has a distinctive structure and the highest ammonia coordination number among all the known MBAs.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c4cc09317h</identifier><identifier>PMID: 25535090</identifier><language>eng</language><publisher>England</publisher><subject>Borohydrides ; Coordination numbers ; Crystals ; Dehydrogenation ; Hydrogen storage materials ; MBA ; Synthesis ; Zirconium</subject><ispartof>Chemical communications (Cambridge, England), 2015-02, Vol.51 (14), p.2794-2797</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c434t-8e639903d0b879d80895a0480be33ffaa164377698f2de30c0f8d366b44e0b6a3</citedby><cites>FETCH-LOGICAL-c434t-8e639903d0b879d80895a0480be33ffaa164377698f2de30c0f8d366b44e0b6a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25535090$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Huang, Jianmei</creatorcontrib><creatorcontrib>Tan, Yingbin</creatorcontrib><creatorcontrib>Su, Jiahao</creatorcontrib><creatorcontrib>Gu, Qinfen</creatorcontrib><creatorcontrib>erný, Radovan</creatorcontrib><creatorcontrib>Ouyang, Liuzhang</creatorcontrib><creatorcontrib>Sun, Dalin</creatorcontrib><creatorcontrib>Yu, Xuebin</creatorcontrib><creatorcontrib>Zhu, Min</creatorcontrib><title>Synthesis, structure and dehydrogenation of zirconium borohydride octaammoniate</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>A new metal borohydride ammoniate (MBA), Zr(BH
4
)
4
·8NH
3
, was synthesized
via
ammoniation of the Zr(BH
4
)
4
crystal. Zr(BH
4
)
4
·8NH
3
has a distinctive structure and the highest coordination number of NH
3
groups among all the known MBAs. This compound could quickly dehydrogenate at 130 °C, enabling it a potential hydrogen storage material.
A novel metal borohydride ammoniate (MBA), Zr(BH
4
)
4
·8NH
3
, has a distinctive structure and the highest ammonia coordination number among all the known MBAs.</description><subject>Borohydrides</subject><subject>Coordination numbers</subject><subject>Crystals</subject><subject>Dehydrogenation</subject><subject>Hydrogen storage materials</subject><subject>MBA</subject><subject>Synthesis</subject><subject>Zirconium</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqF0c1LwzAYBvAgivPr4l2pNxGrad8kTY5S1AmDHVTwVtJ8uMrazCQ9zL_ezk29aS4JPD-ewxOEjjN8lWEQ14oohQVkxWwL7WXASEoJf9levalICyB0hPZDeMPDySjfRaOcUqBY4D00fVx2cWZCEy6TEH2vYu9NIjudaDNbau9eTSdj47rE2eSj8cp1Td8mtfNuFTfaJE5FKdt2CGQ0h2jHynkwR5v7AD3f3T6V43QyvX8obyapIkBiyg0DITBoXPNCaI65oBITjmsDYK2UGSNQFExwm2sDWGHLNTBWE2JwzSQcoPN178K7996EWLVNUGY-l51xfagyLmDoLGj-P2U0J5TivBjoxZoq70LwxlYL37TSL6sMV6utq5KU5dfW4wGfbnr7ujX6h36PO4CzNfBB_aS_n1UttB3MyV8GPgGAyI7-</recordid><startdate>20150218</startdate><enddate>20150218</enddate><creator>Huang, Jianmei</creator><creator>Tan, Yingbin</creator><creator>Su, Jiahao</creator><creator>Gu, Qinfen</creator><creator>erný, Radovan</creator><creator>Ouyang, Liuzhang</creator><creator>Sun, Dalin</creator><creator>Yu, Xuebin</creator><creator>Zhu, Min</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20150218</creationdate><title>Synthesis, structure and dehydrogenation of zirconium borohydride octaammoniate</title><author>Huang, Jianmei ; Tan, Yingbin ; Su, Jiahao ; Gu, Qinfen ; erný, Radovan ; Ouyang, Liuzhang ; Sun, Dalin ; Yu, Xuebin ; Zhu, Min</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c434t-8e639903d0b879d80895a0480be33ffaa164377698f2de30c0f8d366b44e0b6a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Borohydrides</topic><topic>Coordination numbers</topic><topic>Crystals</topic><topic>Dehydrogenation</topic><topic>Hydrogen storage materials</topic><topic>MBA</topic><topic>Synthesis</topic><topic>Zirconium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Huang, Jianmei</creatorcontrib><creatorcontrib>Tan, Yingbin</creatorcontrib><creatorcontrib>Su, Jiahao</creatorcontrib><creatorcontrib>Gu, Qinfen</creatorcontrib><creatorcontrib>erný, Radovan</creatorcontrib><creatorcontrib>Ouyang, Liuzhang</creatorcontrib><creatorcontrib>Sun, Dalin</creatorcontrib><creatorcontrib>Yu, Xuebin</creatorcontrib><creatorcontrib>Zhu, Min</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Huang, Jianmei</au><au>Tan, Yingbin</au><au>Su, Jiahao</au><au>Gu, Qinfen</au><au>erný, Radovan</au><au>Ouyang, Liuzhang</au><au>Sun, Dalin</au><au>Yu, Xuebin</au><au>Zhu, Min</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, structure and dehydrogenation of zirconium borohydride octaammoniate</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2015-02-18</date><risdate>2015</risdate><volume>51</volume><issue>14</issue><spage>2794</spage><epage>2797</epage><pages>2794-2797</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>A new metal borohydride ammoniate (MBA), Zr(BH
4
)
4
·8NH
3
, was synthesized
via
ammoniation of the Zr(BH
4
)
4
crystal. Zr(BH
4
)
4
·8NH
3
has a distinctive structure and the highest coordination number of NH
3
groups among all the known MBAs. This compound could quickly dehydrogenate at 130 °C, enabling it a potential hydrogen storage material.
A novel metal borohydride ammoniate (MBA), Zr(BH
4
)
4
·8NH
3
, has a distinctive structure and the highest ammonia coordination number among all the known MBAs.</abstract><cop>England</cop><pmid>25535090</pmid><doi>10.1039/c4cc09317h</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2015-02, Vol.51 (14), p.2794-2797 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_rsc_primary_c4cc09317h |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Borohydrides Coordination numbers Crystals Dehydrogenation Hydrogen storage materials MBA Synthesis Zirconium |
| title | Synthesis, structure and dehydrogenation of zirconium borohydride octaammoniate |
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