Palladium-catalyzed benzothieno[2,3-b]indole formation via dehydrative-dehydrogenative double C-H sulfuration using sulfur powder, indoles and cyclohexanonesElectronic supplementary information (ESI) available. CCDC 1030356. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4cc08370a

Palladium-catalyzed C-S bond formation via dehydrative-dehydrogenative double C-H sulfuration using sulfur powder is described. The dehydrogenated intermediates of cyclohexanones can be trapped to act as efficient aryl sources under an oxygen atmosphere. This procedure provides a novel approach for...

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Hauptverfasser: Liao, Yunfeng, Peng, Yi, Qi, Hongrui, Deng, Guo-Jun, Gong, Hang, Li, Chao-Jun
Format: Artikel
Sprache:eng
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