On the coordination chemistry of phosphinecarboxamide: assessing ligand basicityElectronic supplementary information (ESI) available: Full experimental details, single crystal X-ray diffraction data, NMR and IR spectra, and computational details are provided. CCDC 1014321. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4cc06094f
We describe the coordination chemistry of the primary phosphine PH 2 C(O)NH 2 (phosphinecarboxamide) towards group 6 transition-metals. Experimental and theoretical studies reveal that this novel species has comparable electronic properties to PH 3 . We describe the coordination chemistry of the pri...
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