Generation of aminoborane monomers RR′N&z.dbd;BH2 from amine-boronium cations [RR′NH-BH2L]+: metal catalyst-free formation of polyaminoboranes at ambient temperatureElectronic supplementary information (ESI) available: Experimental and characterising data. CCDC 983367 and 983368. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4cc05145a
Protonation of MeRNH·BH 3 (R = Me or H) with HX (X = B(C 6 F 5 ) 4 , OTf, or Cl), followed by immediate, spontaneous H 2 elimination, yielded the amine-boronium cation salt [MeRNH·BH 2 (OEt 2 )][B(C 6 F 5 ) 4 ] and related polar covalent analogs, MeRNH·BH 2 X (X = OTf or Cl). These species can be de...
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| creator | Metters, Owen J Chapman, Andy M Robertson, Alasdair P. M Woodall, Christopher H Gates, Paul J Wass, Duncan F Manners, Ian |
| description | Protonation of MeRNH·BH
3
(R = Me or H) with HX (X = B(C
6
F
5
)
4
, OTf, or Cl), followed by immediate, spontaneous H
2
elimination, yielded the amine-boronium cation salt [MeRNH·BH
2
(OEt
2
)][B(C
6
F
5
)
4
] and related polar covalent analogs, MeRNH·BH
2
X (X = OTf or Cl). These species can be deprotonated to conveniently generate reactive aminoborane monomers MeRN&z.dbd;BH
2
which oligomerize or polymerize; in the case of MeNH
2
·BH
3
, the two step process gave poly(
N
-methylaminoborane), [MeNH-BH
2
]
n
.
Amine-boronium cations function as precursors to aminoborane monomers, oligomers and polymers. |
| doi_str_mv | 10.1039/c4cc05145a |
| format | Article |
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3
(R = Me or H) with HX (X = B(C
6
F
5
)
4
, OTf, or Cl), followed by immediate, spontaneous H
2
elimination, yielded the amine-boronium cation salt [MeRNH·BH
2
(OEt
2
)][B(C
6
F
5
)
4
] and related polar covalent analogs, MeRNH·BH
2
X (X = OTf or Cl). These species can be deprotonated to conveniently generate reactive aminoborane monomers MeRN&z.dbd;BH
2
which oligomerize or polymerize; in the case of MeNH
2
·BH
3
, the two step process gave poly(
N
-methylaminoborane), [MeNH-BH
2
]
n
.
Amine-boronium cations function as precursors to aminoborane monomers, oligomers and polymers.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c4cc05145a</identifier><language>eng</language><creationdate>2014-09</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Metters, Owen J</creatorcontrib><creatorcontrib>Chapman, Andy M</creatorcontrib><creatorcontrib>Robertson, Alasdair P. M</creatorcontrib><creatorcontrib>Woodall, Christopher H</creatorcontrib><creatorcontrib>Gates, Paul J</creatorcontrib><creatorcontrib>Wass, Duncan F</creatorcontrib><creatorcontrib>Manners, Ian</creatorcontrib><title>Generation of aminoborane monomers RR′N&z.dbd;BH2 from amine-boronium cations [RR′NH-BH2L]+: metal catalyst-free formation of polyaminoboranes at ambient temperatureElectronic supplementary information (ESI) available: Experimental and characterising data. CCDC 983367 and 983368. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4cc05145a</title><description>Protonation of MeRNH·BH
3
(R = Me or H) with HX (X = B(C
6
F
5
)
4
, OTf, or Cl), followed by immediate, spontaneous H
2
elimination, yielded the amine-boronium cation salt [MeRNH·BH
2
(OEt
2
)][B(C
6
F
5
)
4
] and related polar covalent analogs, MeRNH·BH
2
X (X = OTf or Cl). These species can be deprotonated to conveniently generate reactive aminoborane monomers MeRN&z.dbd;BH
2
which oligomerize or polymerize; in the case of MeNH
2
·BH
3
, the two step process gave poly(
N
-methylaminoborane), [MeNH-BH
2
]
n
.
Amine-boronium cations function as precursors to aminoborane monomers, oligomers and polymers.</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFkU1Lw0AQhqMo-HnxLowXUSS1MUlt683Y2oIoqAdBpEw3kzayH2F3K1Y8-Jv8Sf4SN6lYQdC97LDzzPu-w3reVlCvBfWwdcgixupxEMW46K0GYSPy46h5t1TWccs_DqN4xVsz5rHuThA3Vxdez0mSRpsrCSoDFLlUQ6VREggllSBt4Pr64-39cvellg7Tk9PeEWRaiQol37FK5hMBrNIwcD-je74DLx4O2iDIIi_byKfG-pkmgkxp8e1ZKD794WsArRMf5iQtWBJFGW-iqcOJ2dKMgZkUBSfhANRTyOVcbq9z098HfMKc45BTGzrPbj6vUA4oU2Bj1MisezS5HEHqctUgSc4SaDXDsHFcQVXZrEFXaXCKs0Ht4iPnaqSxGLsU5agzh6TfBccpOyYNNE85SwXG7Xt21W_D7z_a8JYz5IY2v-51b7vbuU16vjZsULjYbr3BHA__7-_81R8UaRZ-AqgBtQs</recordid><startdate>20140916</startdate><enddate>20140916</enddate><creator>Metters, Owen J</creator><creator>Chapman, Andy M</creator><creator>Robertson, Alasdair P. M</creator><creator>Woodall, Christopher H</creator><creator>Gates, Paul J</creator><creator>Wass, Duncan F</creator><creator>Manners, Ian</creator><scope/></search><sort><creationdate>20140916</creationdate><title>Generation of aminoborane monomers RR′N&z.dbd;BH2 from amine-boronium cations [RR′NH-BH2L]+: metal catalyst-free formation of polyaminoboranes at ambient temperatureElectronic supplementary information (ESI) available: Experimental and characterising data. CCDC 983367 and 983368. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4cc05145a</title><author>Metters, Owen J ; Chapman, Andy M ; Robertson, Alasdair P. M ; Woodall, Christopher H ; Gates, Paul J ; Wass, Duncan F ; Manners, Ian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c4cc05145a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Metters, Owen J</creatorcontrib><creatorcontrib>Chapman, Andy M</creatorcontrib><creatorcontrib>Robertson, Alasdair P. M</creatorcontrib><creatorcontrib>Woodall, Christopher H</creatorcontrib><creatorcontrib>Gates, Paul J</creatorcontrib><creatorcontrib>Wass, Duncan F</creatorcontrib><creatorcontrib>Manners, Ian</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Metters, Owen J</au><au>Chapman, Andy M</au><au>Robertson, Alasdair P. M</au><au>Woodall, Christopher H</au><au>Gates, Paul J</au><au>Wass, Duncan F</au><au>Manners, Ian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Generation of aminoborane monomers RR′N&z.dbd;BH2 from amine-boronium cations [RR′NH-BH2L]+: metal catalyst-free formation of polyaminoboranes at ambient temperatureElectronic supplementary information (ESI) available: Experimental and characterising data. CCDC 983367 and 983368. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4cc05145a</atitle><date>2014-09-16</date><risdate>2014</risdate><volume>5</volume><issue>81</issue><spage>12146</spage><epage>12149</epage><pages>12146-12149</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Protonation of MeRNH·BH
3
(R = Me or H) with HX (X = B(C
6
F
5
)
4
, OTf, or Cl), followed by immediate, spontaneous H
2
elimination, yielded the amine-boronium cation salt [MeRNH·BH
2
(OEt
2
)][B(C
6
F
5
)
4
] and related polar covalent analogs, MeRNH·BH
2
X (X = OTf or Cl). These species can be deprotonated to conveniently generate reactive aminoborane monomers MeRN&z.dbd;BH
2
which oligomerize or polymerize; in the case of MeNH
2
·BH
3
, the two step process gave poly(
N
-methylaminoborane), [MeNH-BH
2
]
n
.
Amine-boronium cations function as precursors to aminoborane monomers, oligomers and polymers.</abstract><doi>10.1039/c4cc05145a</doi><tpages>4</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| title | Generation of aminoborane monomers RR′N&z.dbd;BH2 from amine-boronium cations [RR′NH-BH2L]+: metal catalyst-free formation of polyaminoboranes at ambient temperatureElectronic supplementary information (ESI) available: Experimental and characterising data. CCDC 983367 and 983368. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4cc05145a |
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