An electron transfer series of octahedral chromium complexes containing a redox non-innocent α-diimine ligandElectronic supplementary information (ESI) available: Preparative and crystallographic and spectroscopic data. CCDC 1000091 and 1000092. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4cc03332a
An electron-transfer series of octahedral α-diimine complexes [( H L Cy ) 3 Cr] n + (BARF) n ( n = 2, 1, 0) has been synthesized and crystallographically characterized. Cyclic voltammetry indicated additional formation of [( H L Cy ) 3 Cr] 3+ . The molecular structures suggested that all redox proce...
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