A trinuclear Zn3(OAc)4-3,3′-bis(aminoimino)binaphthoxide complex for highly efficient catalytic asymmetric iodolactonizationElectronic supplementary information (ESI) available: Procedural and spectral data. CCDC 956608. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4cc02415j

A 3,3′-bis(aminoimino)BINOL ligand was newly designed and synthesized for the formation of a trinuclear Zn complex upon reaction with Zn(OAc) 2 . Using the harmony of the tri-zinc atoms, 1 mol% Zn 3 (OAc) 4 -3,3′-bis(aminoimino)binaphthoxide catalyzed asymmetric iodolactonization in up to 99.9% ee....

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Hauptverfasser:	Arai, Takayoshi, Sugiyama, Noriyuki, Masu, Hyuma, Kado, Sayaka, Yabe, Shinnosuke, Yamanaka, Masahiro
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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