Normal and shear interactions between high grafting density polymer brushes grown by atom transfer radical polymerization

The normal and shear interactions in toluene of polystyrene polymer brushes with ultra-high surface coverage ranging from 15 to 70 mg m 2 formed by atom transfer radical polymerization were measured with a surface force apparatus. Significant hysteresis was observed between compression and separatio...

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Veröffentlicht in:	Soft matter 2013-01, Vol.9 (24), p.5753-5761
Hauptverfasser:	Liao, Wei-Po, Elliott, Ian G, Faller, Roland, Kuhl, Tonya L
Format:	Artikel
Sprache:	eng
Schlagworte:	Brushes Collapse Compressing Entanglement Hysteresis Polymerization Shear Solvents
Online-Zugang:	Volltext
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