Non-directed allylic C-H acetoxylation in the presence of Lewis basic heterocyclesElectronic supplementary information (ESI) available. See DOI: 10.1039/c3sc53414f

We outline a strategy to enable non-directed Pd( ii )-catalyzed C-H functionalization in the presence of Lewis basic heterocycles. In a high-throughput screen of two Pd-catalyzed C-H acetoxylation reactions, the addition of a variety of N -containing heterocycles is found to cause low product conver...

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Hauptverfasser: Malik, Hasnain A, Taylor, Buck L. H, Kerrigan, John R, Grob, Jonathan E, Houk, K. N, Du Bois, J, Hamann, Lawrence G, Patterson, Andrew W
Format: Artikel
Sprache:eng
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