MM quadruple bonds supported by cyanoacrylate ligands. Extending photon harvesting into the near infrared and studies of the MLCT statesElectronic supplementary information (ESI) available: Table S1, Fig. S1-S6. CCDC 919555 and 919556. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3sc50322d
The compounds trans -M 2 (T i PB) 2 ( L ) 2 and trans -M 2 (T i PB) 2 ( L′ ) 2 have been prepared from the reactions between M 2 (T i PB) 4 (T i PB = 2,4,6-triisopropylbenzoate, M = Mo or W) and LH or L′H (∼2 equiv.), respectively, where L = O 2 CC(CN)&z.dbd;CH-C 6 H 4 -NPh 2 and L′ = O 2 CC(CN)...
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