Ring-opening metathesis polymerization of 8-membered cyclic olefins
Ring-opening metathesis polymerization (ROMP) involving 8-membered cyclic olefins, such as the parent molecules cis -cyclooctene (COE) and cis , cis -1,5-cyclooctadiene (COD), leads to various polyalkenamers that have broad potential in a variety of fields. The use of different catalysts and diverse...
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| Veröffentlicht in: | Polymer chemistry 2014-01, Vol.5 (11), p.357-3532 |
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| container_title | Polymer chemistry |
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| creator | Martinez, Henry Ren, Ning Matta, Megan E Hillmyer, Marc A |
| description | Ring-opening metathesis polymerization (ROMP) involving 8-membered cyclic olefins, such as the parent molecules
cis
-cyclooctene (COE) and
cis
,
cis
-1,5-cyclooctadiene (COD), leads to various polyalkenamers that have broad potential in a variety of fields. The use of different catalysts and diverse functionalized monomers allows for control over molar mass and architecture in the resultant polymers. We review the ROMP of unsubstituted and substituted COE and COD to tune the properties of the resultant homopolymers and copolymers. Starting with a survey of homopolymers, we report the strengths and limitations of the ROMP of functionalized 8-membered ring olefins. Then we show how these monomers are used to control crystallinity, hydrophobicity and morphology, in various types of copolymers.
Ring-opening metathesis polymerization (ROMP) of 8-membered cyclic olefins, such as the parent molecules
cis
-cyclooctene (COE) and
cis
,
cis
-1,5-cyclooctadiene (COD), leads to a range of polyalkenamers that have utility in a variety of applications. |
| doi_str_mv | 10.1039/c3py01787g |
| format | Article |
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cis
-cyclooctene (COE) and
cis
,
cis
-1,5-cyclooctadiene (COD), leads to various polyalkenamers that have broad potential in a variety of fields. The use of different catalysts and diverse functionalized monomers allows for control over molar mass and architecture in the resultant polymers. We review the ROMP of unsubstituted and substituted COE and COD to tune the properties of the resultant homopolymers and copolymers. Starting with a survey of homopolymers, we report the strengths and limitations of the ROMP of functionalized 8-membered ring olefins. Then we show how these monomers are used to control crystallinity, hydrophobicity and morphology, in various types of copolymers.
Ring-opening metathesis polymerization (ROMP) of 8-membered cyclic olefins, such as the parent molecules
cis
-cyclooctene (COE) and
cis
,
cis
-1,5-cyclooctadiene (COD), leads to a range of polyalkenamers that have utility in a variety of applications.</description><identifier>ISSN: 1759-9954</identifier><identifier>EISSN: 1759-9962</identifier><identifier>DOI: 10.1039/c3py01787g</identifier><language>eng</language><ispartof>Polymer chemistry, 2014-01, Vol.5 (11), p.357-3532</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c345t-1d8dee6def16995d13a31de21bab3a30a663bc0af2ebe50f33780c33b7a22bd03</citedby><cites>FETCH-LOGICAL-c345t-1d8dee6def16995d13a31de21bab3a30a663bc0af2ebe50f33780c33b7a22bd03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Martinez, Henry</creatorcontrib><creatorcontrib>Ren, Ning</creatorcontrib><creatorcontrib>Matta, Megan E</creatorcontrib><creatorcontrib>Hillmyer, Marc A</creatorcontrib><title>Ring-opening metathesis polymerization of 8-membered cyclic olefins</title><title>Polymer chemistry</title><description>Ring-opening metathesis polymerization (ROMP) involving 8-membered cyclic olefins, such as the parent molecules
cis
-cyclooctene (COE) and
cis
,
cis
-1,5-cyclooctadiene (COD), leads to various polyalkenamers that have broad potential in a variety of fields. The use of different catalysts and diverse functionalized monomers allows for control over molar mass and architecture in the resultant polymers. We review the ROMP of unsubstituted and substituted COE and COD to tune the properties of the resultant homopolymers and copolymers. Starting with a survey of homopolymers, we report the strengths and limitations of the ROMP of functionalized 8-membered ring olefins. Then we show how these monomers are used to control crystallinity, hydrophobicity and morphology, in various types of copolymers.
Ring-opening metathesis polymerization (ROMP) of 8-membered cyclic olefins, such as the parent molecules
cis
-cyclooctene (COE) and
cis
,
cis
-1,5-cyclooctadiene (COD), leads to a range of polyalkenamers that have utility in a variety of applications.</description><issn>1759-9954</issn><issn>1759-9962</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp9kM1LxDAUxIMouKx78S7EqxBN-tq0PUrxCxYE0XPJx8saaZuS9FL_eisruzfnMgPvx2MYQi4FvxUc6jsD48xFWZW7E7ISZVGzupbZ6SEX-TnZpPTFF4HIM5Ar0rz5YcfCiMPitMdJTZ-YfKJj6OYeo_9Wkw8DDY5WrMdeY0RLzWw6b2jo0PkhXZAzp7qEmz9fk4_Hh_fmmW1fn16a-y0zkBcTE7ayiNKiE3IpYwUoEBYzoZVeIldSgjZcuQw1FtwBlBU3ALpUWaYthzW52f81MaQU0bVj9L2Kcyt4-7tAe1xgga_3cEzmwB3v7Wjdwlz9x8APAp9lcw</recordid><startdate>20140101</startdate><enddate>20140101</enddate><creator>Martinez, Henry</creator><creator>Ren, Ning</creator><creator>Matta, Megan E</creator><creator>Hillmyer, Marc A</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20140101</creationdate><title>Ring-opening metathesis polymerization of 8-membered cyclic olefins</title><author>Martinez, Henry ; Ren, Ning ; Matta, Megan E ; Hillmyer, Marc A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c345t-1d8dee6def16995d13a31de21bab3a30a663bc0af2ebe50f33780c33b7a22bd03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Martinez, Henry</creatorcontrib><creatorcontrib>Ren, Ning</creatorcontrib><creatorcontrib>Matta, Megan E</creatorcontrib><creatorcontrib>Hillmyer, Marc A</creatorcontrib><collection>CrossRef</collection><jtitle>Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Martinez, Henry</au><au>Ren, Ning</au><au>Matta, Megan E</au><au>Hillmyer, Marc A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ring-opening metathesis polymerization of 8-membered cyclic olefins</atitle><jtitle>Polymer chemistry</jtitle><date>2014-01-01</date><risdate>2014</risdate><volume>5</volume><issue>11</issue><spage>357</spage><epage>3532</epage><pages>357-3532</pages><issn>1759-9954</issn><eissn>1759-9962</eissn><abstract>Ring-opening metathesis polymerization (ROMP) involving 8-membered cyclic olefins, such as the parent molecules
cis
-cyclooctene (COE) and
cis
,
cis
-1,5-cyclooctadiene (COD), leads to various polyalkenamers that have broad potential in a variety of fields. The use of different catalysts and diverse functionalized monomers allows for control over molar mass and architecture in the resultant polymers. We review the ROMP of unsubstituted and substituted COE and COD to tune the properties of the resultant homopolymers and copolymers. Starting with a survey of homopolymers, we report the strengths and limitations of the ROMP of functionalized 8-membered ring olefins. Then we show how these monomers are used to control crystallinity, hydrophobicity and morphology, in various types of copolymers.
Ring-opening metathesis polymerization (ROMP) of 8-membered cyclic olefins, such as the parent molecules
cis
-cyclooctene (COE) and
cis
,
cis
-1,5-cyclooctadiene (COD), leads to a range of polyalkenamers that have utility in a variety of applications.</abstract><doi>10.1039/c3py01787g</doi><tpages>26</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1759-9954 |
| ispartof | Polymer chemistry, 2014-01, Vol.5 (11), p.357-3532 |
| issn | 1759-9954 1759-9962 |
| language | eng |
| recordid | cdi_rsc_primary_c3py01787g |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Ring-opening metathesis polymerization of 8-membered cyclic olefins |
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