Spontaneous shape changes in polymersomes via polymer/polymer segregationElectronic supplementary information (ESI) available: The ESI contains synthesis schemes of H2N-PAA-b-PBD 8, DNB-PEG-PBD 11 and Fl-PEG35-PBD11013, and analytical details of all constructed polymers. See DOI: 10.1039/c3py00906h
We demonstrate that nanometre-sized polymer vesicles (polymersomes) assembled from two dissimilar diblock copolymers can undergo shape changes, driven by strong lateral polymer/polymer segregation within the membrane. The two particular block copolymers consisted of identical hydrophobic fragments t...
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