Evaluation of thiocarbonyl and thioester moieties as thiol protecting groups for controlled radical polymerizationElectronic supplementary information (ESI) available: 1H NMR and/or UV/Vis spectra of model molecules, model polymers, protected, deprotected and functional copolymers. See DOI: 10.1039/c3py00754e
Thiol chemistry is a versatile and powerful tool for the preparation of functional polymers and materials. In that regard, xanthate, dithiocarbamate and thioacetate moieties were evaluated as thiol protecting groups for radical polymerization. Model reactions were conducted to study the effect of th...
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