Hierarchical self-assembly of amphiphilic calix[6]arene wheels and viologen axles in waterDedicated to Prof. Maurizio Prato on the occasion of his C60th birthday.Electronic supplementary information (ESI) available: NMR spectra, UV-visible titration experiments, determination of critical aggregation concentration, Cryo-TEM, 5(6)-carboxyfluorescein (CF) release and DLS analysis of CA8 and CA18 aggregates. See DOI: 10.1039/c3ob40739j

Hierarchical self-assembly of amphiphilic calix[6]arene wheels and viologen axles in waterDedicated to Prof. Maurizio Prato on the occasion of his C60th birthday.Electronic supplementary information (ESI) available: NMR spectra, UV-visible titration experiments, determination of critical aggregation concentration, Cryo-TEM, 5(6)-carboxyfluorescein (CF) release and DLS analysis of CA8 and CA18 aggregates. See DOI: 10.1039/c3ob40739j

We have designed and synthesized two amphiphilic calix[6]arene derivatives, CA8 and CA18 , that combine the potential to act as wheel components for pseudorotaxane structures with the self-assembly features typical of surfactant molecules in aqueous solution. Their endo-cavity recognition and self-a...

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Hauptverfasser: Bussolati, Rocco, Carrieri, Pasquale, Secchi, Andrea, Arduini, Arturo, Credi, Alberto, Semeraro, Monica, Venturi, Margherita, Silvi, Serena, Velluto, Diana, Zappacosta, Romina, Fontana, Antonella
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Sprache:eng
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