TTF-fluorene dyads and their M(CN)2− (M = Ag, Au) salts designed for photoresponsive conducting materialsElectronic supplementary information (ESI) available: NMR charts of dyads 1a-d, 2a-b, and UV-Vis simulated spectra of 1a and 2a calculated on the basis of the TD-DFT method. CCDC 953471-953473. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3nj00979c

TTF-fluorene dyads and their M(CN)2− (M = Ag, Au) salts designed for photoresponsive conducting materialsElectronic supplementary information (ESI) available: NMR charts of dyads 1a-d, 2a-b, and UV-Vis simulated spectra of 1a and 2a calculated on the basis of the TD-DFT method. CCDC 953471-953473. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3nj00979c

To explore photoresponsive conducting materials, we developed new tetrathiafulvalene (TTF)-fluorene D-A dyads with a σ-bonded thiomethylene spacer ( 1a-d ) or a π-conjugated ethylene spacer ( 2a-b ) and reported their synthesis, electrochemical and optical properties. Fluorescence studies suggested...

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Hauptverfasser: Tsujimoto, Keijiro, Ogasawara, Reiko, Kishi, Yosuke, Fujiwara, Hideki
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