Continuous catalyst-free aromatization of γ-terpinene using air as an oxidant
The dehydrogenation of γ-terpinene was studied under catalyst- and solvent-free reaction conditions using air as an oxidant. The dehydrogenation affords p -cymene in good yields in a continuous flow reaction setup. The initial optimization of the reaction parameters showed that the dehydrogenation i...
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| Veröffentlicht in: | Green chemistry : an international journal and green chemistry resource : GC 2013-01, Vol.15 (11), p.323-3235 |
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| container_title | Green chemistry : an international journal and green chemistry resource : GC |
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| creator | Asikainen, Martta Jauhiainen, Olli Aaltonen, Olli Harlin, Ali |
| description | The dehydrogenation of γ-terpinene was studied under catalyst- and solvent-free reaction conditions using air as an oxidant. The dehydrogenation affords
p
-cymene in good yields in a continuous flow reaction setup. The initial optimization of the reaction parameters showed that the dehydrogenation is highly dependent on the vapour/liquid phase equilibrium and the availability of oxygen in the vapour phase.
Dehydrogenation of γ-terpinene to
p
-cymene was achieved in the absence of solvents and catalysts by using air as an oxidant. |
| doi_str_mv | 10.1039/c3gc41224e |
| format | Article |
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p
-cymene in good yields in a continuous flow reaction setup. The initial optimization of the reaction parameters showed that the dehydrogenation is highly dependent on the vapour/liquid phase equilibrium and the availability of oxygen in the vapour phase.
Dehydrogenation of γ-terpinene to
p
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p
-cymene in good yields in a continuous flow reaction setup. The initial optimization of the reaction parameters showed that the dehydrogenation is highly dependent on the vapour/liquid phase equilibrium and the availability of oxygen in the vapour phase.
Dehydrogenation of γ-terpinene to
p
-cymene was achieved in the absence of solvents and catalysts by using air as an oxidant.</description><subject>Alicyclic compounds, terpenoids, prostaglandins, steroids</subject><subject>Availability</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Continuous flow</subject><subject>Dehydrogenation</subject><subject>Exact sciences and technology</subject><subject>Optimization</subject><subject>Organic chemistry</subject><subject>Oxidants</subject><subject>Oxidizing agents</subject><subject>Preparations and properties</subject><subject>Terpenoids</subject><subject>Vapour</subject><issn>1463-9262</issn><issn>1463-9270</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9UMtKA0EQHETBGL14F8aDIMLqvHZ29yjBFwS96HnpzCOMbGbjzCwYf8v_8JucEIl4EbrphqqupgqhY0ouKeHNleJzJShjwuygERWSFw2ryO52l2wfHcT4SgillRQj9DjpfXJ-6IeIFSToVjEVNhiDIfQLSO4jd-9xb_HXZ5FMWDpvvMFDdH6OwQUMEUPG350Gnw7RnoUumqOfOUYvtzfPk_ti-nT3MLmeFooLlgo-09pKC7WYcao16BmvgZbZATDBRVNJVpmaNoqzpsmleUlsWXJSG8UrXfIxOt_oLkP_NpiY2oWLynQdeJOttLSU2aFkZZ2pFxuqCn2Mwdh2GdwCwqqlpF2H1v6GlslnP7oQFXQ2gFcubi9YVVeNFOv_JxteiGqL_tE5_Q9vl9rybzWPgho</recordid><startdate>20130101</startdate><enddate>20130101</enddate><creator>Asikainen, Martta</creator><creator>Jauhiainen, Olli</creator><creator>Aaltonen, Olli</creator><creator>Harlin, Ali</creator><general>Royal Society of Chemistry</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20130101</creationdate><title>Continuous catalyst-free aromatization of γ-terpinene using air as an oxidant</title><author>Asikainen, Martta ; Jauhiainen, Olli ; Aaltonen, Olli ; Harlin, Ali</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c342t-3bddf6fa84b31ddadb38a15039a243497627e819c3299299d350f55308ec37d53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Alicyclic compounds, terpenoids, prostaglandins, steroids</topic><topic>Availability</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Continuous flow</topic><topic>Dehydrogenation</topic><topic>Exact sciences and technology</topic><topic>Optimization</topic><topic>Organic chemistry</topic><topic>Oxidants</topic><topic>Oxidizing agents</topic><topic>Preparations and properties</topic><topic>Terpenoids</topic><topic>Vapour</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Asikainen, Martta</creatorcontrib><creatorcontrib>Jauhiainen, Olli</creatorcontrib><creatorcontrib>Aaltonen, Olli</creatorcontrib><creatorcontrib>Harlin, Ali</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Asikainen, Martta</au><au>Jauhiainen, Olli</au><au>Aaltonen, Olli</au><au>Harlin, Ali</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Continuous catalyst-free aromatization of γ-terpinene using air as an oxidant</atitle><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle><date>2013-01-01</date><risdate>2013</risdate><volume>15</volume><issue>11</issue><spage>323</spage><epage>3235</epage><pages>323-3235</pages><issn>1463-9262</issn><eissn>1463-9270</eissn><abstract>The dehydrogenation of γ-terpinene was studied under catalyst- and solvent-free reaction conditions using air as an oxidant. The dehydrogenation affords
p
-cymene in good yields in a continuous flow reaction setup. The initial optimization of the reaction parameters showed that the dehydrogenation is highly dependent on the vapour/liquid phase equilibrium and the availability of oxygen in the vapour phase.
Dehydrogenation of γ-terpinene to
p
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| fulltext | fulltext |
| identifier | ISSN: 1463-9262 |
| ispartof | Green chemistry : an international journal and green chemistry resource : GC, 2013-01, Vol.15 (11), p.323-3235 |
| issn | 1463-9262 1463-9270 |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Alicyclic compounds, terpenoids, prostaglandins, steroids Availability Catalysts Chemistry Continuous flow Dehydrogenation Exact sciences and technology Optimization Organic chemistry Oxidants Oxidizing agents Preparations and properties Terpenoids Vapour |
| title | Continuous catalyst-free aromatization of γ-terpinene using air as an oxidant |
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