Synthesis and properties of full bio-based thermosetting resins from rosin acid and soybean oil: the role of rosin acid derivatives
Two kinds of rosin acid derivatives were synthesized to serve as the rigid monomers to copolymerize with acrylated epoxidized soybean oil (AESO). Full bio-based thermosetting resins with satisfactory properties were then prepared. For comparison, petroleum-based divinylbenzene (DVB) was also used to...
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| Veröffentlicht in: | Green chemistry : an international journal and green chemistry resource : GC 2013-01, Vol.15 (5), p.13-131 |
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| creator | Ma, Qiangqiang Liu, Xiaoqing Zhang, Ruoyu Zhu, Jin Jiang, Yanhua |
| description | Two kinds of rosin acid derivatives were synthesized to serve as the rigid monomers to copolymerize with acrylated epoxidized soybean oil (AESO). Full bio-based thermosetting resins with satisfactory properties were then prepared. For comparison, petroleum-based divinylbenzene (DVB) was also used to copolymerize with the same AESO. The chemical structures of the synthesized rosin derivatives were confirmed by
1
H NMR,
13
C NMR and FT-IR before polymerization. The mechanical and thermal properties of the resulting thermosets were investigated by differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA) and thermogravimetric analysis (TGA). Results demonstrated that the glass transition temperatures, tensile strength and modulus of the cured AESO were significantly improved after copolymerization with the rosin derivatives. The rosin acid derivatives showed great potential to replace petroleum-based rigid compounds for preparing soybean oil-based thermosets. The important information about how to design and synthesize more renewable thermosets with satisfactory properties was provided in this study.
Rosin-based monomers were synthesized and served as petroleum-based rigid compound substitutions to copolymerize with soybean oil derivatives. Full bio-based thermosetting resins were then prepared. |
| doi_str_mv | 10.1039/c3gc00095h |
| format | Article |
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1
H NMR,
13
C NMR and FT-IR before polymerization. The mechanical and thermal properties of the resulting thermosets were investigated by differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA) and thermogravimetric analysis (TGA). Results demonstrated that the glass transition temperatures, tensile strength and modulus of the cured AESO were significantly improved after copolymerization with the rosin derivatives. The rosin acid derivatives showed great potential to replace petroleum-based rigid compounds for preparing soybean oil-based thermosets. The important information about how to design and synthesize more renewable thermosets with satisfactory properties was provided in this study.
Rosin-based monomers were synthesized and served as petroleum-based rigid compound substitutions to copolymerize with soybean oil derivatives. Full bio-based thermosetting resins were then prepared.</description><identifier>ISSN: 1463-9262</identifier><identifier>EISSN: 1463-9270</identifier><identifier>DOI: 10.1039/c3gc00095h</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Applied sciences ; Copolymerization ; Derivatives ; Differential scanning calorimetry ; Exact sciences and technology ; Industrial polymers. Preparations ; Nuclear magnetic resonance ; Polymer industry, paints, wood ; Polymerization ; Rosin ; Soybeans ; Technology of polymers ; Thermosets ; Thermosetting resins</subject><ispartof>Green chemistry : an international journal and green chemistry resource : GC, 2013-01, Vol.15 (5), p.13-131</ispartof><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c342t-24cc4f7fa0c1d811492a62871a983cbf9dc06b7ef06d38f8373b39106b5149063</citedby><cites>FETCH-LOGICAL-c342t-24cc4f7fa0c1d811492a62871a983cbf9dc06b7ef06d38f8373b39106b5149063</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27302546$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Ma, Qiangqiang</creatorcontrib><creatorcontrib>Liu, Xiaoqing</creatorcontrib><creatorcontrib>Zhang, Ruoyu</creatorcontrib><creatorcontrib>Zhu, Jin</creatorcontrib><creatorcontrib>Jiang, Yanhua</creatorcontrib><title>Synthesis and properties of full bio-based thermosetting resins from rosin acid and soybean oil: the role of rosin acid derivatives</title><title>Green chemistry : an international journal and green chemistry resource : GC</title><description>Two kinds of rosin acid derivatives were synthesized to serve as the rigid monomers to copolymerize with acrylated epoxidized soybean oil (AESO). Full bio-based thermosetting resins with satisfactory properties were then prepared. For comparison, petroleum-based divinylbenzene (DVB) was also used to copolymerize with the same AESO. The chemical structures of the synthesized rosin derivatives were confirmed by
1
H NMR,
13
C NMR and FT-IR before polymerization. The mechanical and thermal properties of the resulting thermosets were investigated by differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA) and thermogravimetric analysis (TGA). Results demonstrated that the glass transition temperatures, tensile strength and modulus of the cured AESO were significantly improved after copolymerization with the rosin derivatives. The rosin acid derivatives showed great potential to replace petroleum-based rigid compounds for preparing soybean oil-based thermosets. The important information about how to design and synthesize more renewable thermosets with satisfactory properties was provided in this study.
Rosin-based monomers were synthesized and served as petroleum-based rigid compound substitutions to copolymerize with soybean oil derivatives. Full bio-based thermosetting resins were then prepared.</description><subject>Applied sciences</subject><subject>Copolymerization</subject><subject>Derivatives</subject><subject>Differential scanning calorimetry</subject><subject>Exact sciences and technology</subject><subject>Industrial polymers. Preparations</subject><subject>Nuclear magnetic resonance</subject><subject>Polymer industry, paints, wood</subject><subject>Polymerization</subject><subject>Rosin</subject><subject>Soybeans</subject><subject>Technology of polymers</subject><subject>Thermosets</subject><subject>Thermosetting resins</subject><issn>1463-9262</issn><issn>1463-9270</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9kM9LwzAUx4soOKcX70I8CCJU86NrGm8y_AUDD-q5pPmxRdqm5nWDnf3HTZ1snjzlkff5fl7ykuSU4GuCmbhRbK4wxmKy2EtGJMtZKijH-9s6p4fJEcAHxoTwPBslX6_rtl8YcIBkq1EXfGdC7wwgb5Fd1jWqnE8rCUajyIXGg-l7185RiKEWkA2-QcHHGknl9I8F_LoyskXe1bdDKvZrMwj_cNoEt5K9Wxk4Tg6srMGc_J7j5P3h_m36lM5eHp-nd7NUsYz2Kc2Uyiy3EiuiC0IyQWVOC06kKJiqrNAK5xU3FueaFbZgnFVMkHg3iSzO2Ti53HjjLz-XBvqycaBMXcvW-CWUhAkhSEE4jejVBlXxyRCMLbvgGhnWJcHlsOlyt-kIX_x6JShZ2yBb5WCboJxhOsmG-ecbLoDadneestM2Mmf_MewbsIqU7w</recordid><startdate>20130101</startdate><enddate>20130101</enddate><creator>Ma, Qiangqiang</creator><creator>Liu, Xiaoqing</creator><creator>Zhang, Ruoyu</creator><creator>Zhu, Jin</creator><creator>Jiang, Yanhua</creator><general>Royal Society of Chemistry</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20130101</creationdate><title>Synthesis and properties of full bio-based thermosetting resins from rosin acid and soybean oil: the role of rosin acid derivatives</title><author>Ma, Qiangqiang ; Liu, Xiaoqing ; Zhang, Ruoyu ; Zhu, Jin ; Jiang, Yanhua</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c342t-24cc4f7fa0c1d811492a62871a983cbf9dc06b7ef06d38f8373b39106b5149063</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Applied sciences</topic><topic>Copolymerization</topic><topic>Derivatives</topic><topic>Differential scanning calorimetry</topic><topic>Exact sciences and technology</topic><topic>Industrial polymers. Preparations</topic><topic>Nuclear magnetic resonance</topic><topic>Polymer industry, paints, wood</topic><topic>Polymerization</topic><topic>Rosin</topic><topic>Soybeans</topic><topic>Technology of polymers</topic><topic>Thermosets</topic><topic>Thermosetting resins</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ma, Qiangqiang</creatorcontrib><creatorcontrib>Liu, Xiaoqing</creatorcontrib><creatorcontrib>Zhang, Ruoyu</creatorcontrib><creatorcontrib>Zhu, Jin</creatorcontrib><creatorcontrib>Jiang, Yanhua</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ma, Qiangqiang</au><au>Liu, Xiaoqing</au><au>Zhang, Ruoyu</au><au>Zhu, Jin</au><au>Jiang, Yanhua</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and properties of full bio-based thermosetting resins from rosin acid and soybean oil: the role of rosin acid derivatives</atitle><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle><date>2013-01-01</date><risdate>2013</risdate><volume>15</volume><issue>5</issue><spage>13</spage><epage>131</epage><pages>13-131</pages><issn>1463-9262</issn><eissn>1463-9270</eissn><abstract>Two kinds of rosin acid derivatives were synthesized to serve as the rigid monomers to copolymerize with acrylated epoxidized soybean oil (AESO). Full bio-based thermosetting resins with satisfactory properties were then prepared. For comparison, petroleum-based divinylbenzene (DVB) was also used to copolymerize with the same AESO. The chemical structures of the synthesized rosin derivatives were confirmed by
1
H NMR,
13
C NMR and FT-IR before polymerization. The mechanical and thermal properties of the resulting thermosets were investigated by differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA) and thermogravimetric analysis (TGA). Results demonstrated that the glass transition temperatures, tensile strength and modulus of the cured AESO were significantly improved after copolymerization with the rosin derivatives. The rosin acid derivatives showed great potential to replace petroleum-based rigid compounds for preparing soybean oil-based thermosets. The important information about how to design and synthesize more renewable thermosets with satisfactory properties was provided in this study.
Rosin-based monomers were synthesized and served as petroleum-based rigid compound substitutions to copolymerize with soybean oil derivatives. Full bio-based thermosetting resins were then prepared.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c3gc00095h</doi><tpages>11</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1463-9262 |
| ispartof | Green chemistry : an international journal and green chemistry resource : GC, 2013-01, Vol.15 (5), p.13-131 |
| issn | 1463-9262 1463-9270 |
| language | eng |
| recordid | cdi_rsc_primary_c3gc00095h |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Applied sciences Copolymerization Derivatives Differential scanning calorimetry Exact sciences and technology Industrial polymers. Preparations Nuclear magnetic resonance Polymer industry, paints, wood Polymerization Rosin Soybeans Technology of polymers Thermosets Thermosetting resins |
| title | Synthesis and properties of full bio-based thermosetting resins from rosin acid and soybean oil: the role of rosin acid derivatives |
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