Homo- and heteropolymetallic 3-(2-pyridyl)pyrazolate manganese and rhenium complexesCCDC 873520, 974910, 873521, 974911, 873522 and 873523. For crystallographic data in CIF or other electronic format see DOI: 10.1039/c3dt53439a

fac -[MBr(CO) 3 (pypzH)] (M = Mn, Re; pypzH = (3-(2-pyridyl)pyrazole) complexes are prepared from fac -[MBr(CO) 3 (NCMe) 2 ] and pypzH. The result of their deprotonation depends on the metallic substrate: the rhenium complex affords cleanly the bimetallic compound [ fac -{Re(CO) 3 (μ 2 -pypz)}] 2 (μ...

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Hauptverfasser:	Arroyo, Marta, Gómez-Iglesias, Patricia, Antón, Noelia, García-Rodríguez, Raúl, Alegria, Elisabete C. B. A, Pombeiro, Armando J. L, Miguel, Daniel, Villafañe, Fernando
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Sprache:	eng
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