Binuclear ruthenium η6-arene complexes with tetradentate N,S-ligands containing the ortho-aminothiophenol motifElectronic supplementary information (ESI) available. CCDC 967363. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3dt53075b
A series of cationic binuclear (η 6 -cymene-Ru) 2 complexes with N 2 S 2 -ligands were synthesized in 64% to 85% yield by reaction of [Ru(η 6 -cymene)Cl 2 ] 2 with bis-S , S ′-( ortho -aminothiophenol)-xylenes as BF 4 − and PF 6 − salts. The compounds were studied using NMR, HRMS, UV-vis and IR spec...
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