Gold(i) complexes with heteroaryl phosphine ligandsElectronic supplementary information (ESI) available. CCDC 960836-960840. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3dt52893f
Gold( i ) complexes ligated by phosphines with N -heterocycles in the periphery were prepared. First the synthesis of the ligands N -(diphenylphosphino)-4-(pyridin-2-yl)pyrimidin-2-amine (Hpypya) and N -(diphenylphosphino)-4-phenylpyrimidin-2-amine (Hphpya) are reported. These two compounds together...
Gespeichert in:
| Hauptverfasser: | , , , , , |
|---|---|
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 245 |
|---|---|
| container_issue | 6 |
| container_start_page | 2397 |
| container_title | |
| container_volume | 43 |
| creator | Sarcher, Christian Farsadpour, Saeid Taghizadeh Ghoochany, Leila Sun, Yu Thiel, Werner R Roesky, Peter W |
| description | Gold(
i
) complexes ligated by phosphines with
N
-heterocycles in the periphery were prepared. First the synthesis of the ligands
N
-(diphenylphosphino)-4-(pyridin-2-yl)pyrimidin-2-amine (Hpypya) and
N
-(diphenylphosphino)-4-phenylpyrimidin-2-amine (Hphpya) are reported. These two compounds together with the related but earlier published ligands 3-(2-(diphenylphosphino)phenyl)-1
H
-pyrazole (Hph3py) and 5-(4-(diphenylphosphino)phenyl)-1
H
-pyrazole (Hph5py) were reacted with [(tht)AuCl] and [Au(tht)
2
]ClO
4
to give the heteroleptic complexes [(L)AuCl] and the homoleptic compounds [(L)
2
Au]ClO
4
(L = Hpypya, Hphpya, Hph3py, and Hph5py). Single crystal X-ray diffraction studies revealed that the heteroleptic complexes form hydrogen bonds between two
N
-heterocycles of neighboring complexes resulting in dimeric structures. The homoleptic complexes show a different behavior.
Homoleptic and heteroleptic gold(
i
) complexes ligated by phosphines with
N
-heterocycles in the periphery were prepared. |
| doi_str_mv | 10.1039/c3dt52893f |
| format | Article |
| fullrecord | <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_c3dt52893f</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c3dt52893f</sourcerecordid><originalsourceid>FETCH-rsc_primary_c3dt52893f3</originalsourceid><addsrcrecordid>eNp9kL1PwzAQxS0EEqWwsCMdWzskOB9NG9Y0gUwMsEfGuTRGTmzZ5qP_a_8YXIHogNTpnXS_e-_pCLmOaBjRJL_jSesW8SpPuhMyidLlMsjjJD39m-PsnFxY-0ZpHNNFPCG7ByXbmZgDV4OW-IUWPoXroUeHRjGzlaB7ZXUvRgQpNmxsbSmRO6NGwcG-a3814Og8CmLslBmYE2qEWflcz4F9MCHZq8QQimJdQJ7RVZIFe0lpCJUy4DnwrsDN1jompdoY5uM4tMwxbwlFXYHnlOvRAB6yf7LAIsL6qb6H_z-4JGcdkxavfnVKbqrypXgMjOWNNmLwpZsDnkzJ7bF9o9s9c9zjG19vefM</addsrcrecordid><sourcetype>Enrichment Source</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Gold(i) complexes with heteroaryl phosphine ligandsElectronic supplementary information (ESI) available. CCDC 960836-960840. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3dt52893f</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Sarcher, Christian ; Farsadpour, Saeid ; Taghizadeh Ghoochany, Leila ; Sun, Yu ; Thiel, Werner R ; Roesky, Peter W</creator><creatorcontrib>Sarcher, Christian ; Farsadpour, Saeid ; Taghizadeh Ghoochany, Leila ; Sun, Yu ; Thiel, Werner R ; Roesky, Peter W</creatorcontrib><description>Gold(
i
) complexes ligated by phosphines with
N
-heterocycles in the periphery were prepared. First the synthesis of the ligands
N
-(diphenylphosphino)-4-(pyridin-2-yl)pyrimidin-2-amine (Hpypya) and
N
-(diphenylphosphino)-4-phenylpyrimidin-2-amine (Hphpya) are reported. These two compounds together with the related but earlier published ligands 3-(2-(diphenylphosphino)phenyl)-1
H
-pyrazole (Hph3py) and 5-(4-(diphenylphosphino)phenyl)-1
H
-pyrazole (Hph5py) were reacted with [(tht)AuCl] and [Au(tht)
2
]ClO
4
to give the heteroleptic complexes [(L)AuCl] and the homoleptic compounds [(L)
2
Au]ClO
4
(L = Hpypya, Hphpya, Hph3py, and Hph5py). Single crystal X-ray diffraction studies revealed that the heteroleptic complexes form hydrogen bonds between two
N
-heterocycles of neighboring complexes resulting in dimeric structures. The homoleptic complexes show a different behavior.
Homoleptic and heteroleptic gold(
i
) complexes ligated by phosphines with
N
-heterocycles in the periphery were prepared.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c3dt52893f</identifier><language>eng</language><creationdate>2014-01</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Sarcher, Christian</creatorcontrib><creatorcontrib>Farsadpour, Saeid</creatorcontrib><creatorcontrib>Taghizadeh Ghoochany, Leila</creatorcontrib><creatorcontrib>Sun, Yu</creatorcontrib><creatorcontrib>Thiel, Werner R</creatorcontrib><creatorcontrib>Roesky, Peter W</creatorcontrib><title>Gold(i) complexes with heteroaryl phosphine ligandsElectronic supplementary information (ESI) available. CCDC 960836-960840. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3dt52893f</title><description>Gold(
i
) complexes ligated by phosphines with
N
-heterocycles in the periphery were prepared. First the synthesis of the ligands
N
-(diphenylphosphino)-4-(pyridin-2-yl)pyrimidin-2-amine (Hpypya) and
N
-(diphenylphosphino)-4-phenylpyrimidin-2-amine (Hphpya) are reported. These two compounds together with the related but earlier published ligands 3-(2-(diphenylphosphino)phenyl)-1
H
-pyrazole (Hph3py) and 5-(4-(diphenylphosphino)phenyl)-1
H
-pyrazole (Hph5py) were reacted with [(tht)AuCl] and [Au(tht)
2
]ClO
4
to give the heteroleptic complexes [(L)AuCl] and the homoleptic compounds [(L)
2
Au]ClO
4
(L = Hpypya, Hphpya, Hph3py, and Hph5py). Single crystal X-ray diffraction studies revealed that the heteroleptic complexes form hydrogen bonds between two
N
-heterocycles of neighboring complexes resulting in dimeric structures. The homoleptic complexes show a different behavior.
Homoleptic and heteroleptic gold(
i
) complexes ligated by phosphines with
N
-heterocycles in the periphery were prepared.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNp9kL1PwzAQxS0EEqWwsCMdWzskOB9NG9Y0gUwMsEfGuTRGTmzZ5qP_a_8YXIHogNTpnXS_e-_pCLmOaBjRJL_jSesW8SpPuhMyidLlMsjjJD39m-PsnFxY-0ZpHNNFPCG7ByXbmZgDV4OW-IUWPoXroUeHRjGzlaB7ZXUvRgQpNmxsbSmRO6NGwcG-a3814Og8CmLslBmYE2qEWflcz4F9MCHZq8QQimJdQJ7RVZIFe0lpCJUy4DnwrsDN1jompdoY5uM4tMwxbwlFXYHnlOvRAB6yf7LAIsL6qb6H_z-4JGcdkxavfnVKbqrypXgMjOWNNmLwpZsDnkzJ7bF9o9s9c9zjG19vefM</recordid><startdate>20140114</startdate><enddate>20140114</enddate><creator>Sarcher, Christian</creator><creator>Farsadpour, Saeid</creator><creator>Taghizadeh Ghoochany, Leila</creator><creator>Sun, Yu</creator><creator>Thiel, Werner R</creator><creator>Roesky, Peter W</creator><scope/></search><sort><creationdate>20140114</creationdate><title>Gold(i) complexes with heteroaryl phosphine ligandsElectronic supplementary information (ESI) available. CCDC 960836-960840. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3dt52893f</title><author>Sarcher, Christian ; Farsadpour, Saeid ; Taghizadeh Ghoochany, Leila ; Sun, Yu ; Thiel, Werner R ; Roesky, Peter W</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c3dt52893f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sarcher, Christian</creatorcontrib><creatorcontrib>Farsadpour, Saeid</creatorcontrib><creatorcontrib>Taghizadeh Ghoochany, Leila</creatorcontrib><creatorcontrib>Sun, Yu</creatorcontrib><creatorcontrib>Thiel, Werner R</creatorcontrib><creatorcontrib>Roesky, Peter W</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sarcher, Christian</au><au>Farsadpour, Saeid</au><au>Taghizadeh Ghoochany, Leila</au><au>Sun, Yu</au><au>Thiel, Werner R</au><au>Roesky, Peter W</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Gold(i) complexes with heteroaryl phosphine ligandsElectronic supplementary information (ESI) available. CCDC 960836-960840. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3dt52893f</atitle><date>2014-01-14</date><risdate>2014</risdate><volume>43</volume><issue>6</issue><spage>2397</spage><epage>245</epage><pages>2397-245</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Gold(
i
) complexes ligated by phosphines with
N
-heterocycles in the periphery were prepared. First the synthesis of the ligands
N
-(diphenylphosphino)-4-(pyridin-2-yl)pyrimidin-2-amine (Hpypya) and
N
-(diphenylphosphino)-4-phenylpyrimidin-2-amine (Hphpya) are reported. These two compounds together with the related but earlier published ligands 3-(2-(diphenylphosphino)phenyl)-1
H
-pyrazole (Hph3py) and 5-(4-(diphenylphosphino)phenyl)-1
H
-pyrazole (Hph5py) were reacted with [(tht)AuCl] and [Au(tht)
2
]ClO
4
to give the heteroleptic complexes [(L)AuCl] and the homoleptic compounds [(L)
2
Au]ClO
4
(L = Hpypya, Hphpya, Hph3py, and Hph5py). Single crystal X-ray diffraction studies revealed that the heteroleptic complexes form hydrogen bonds between two
N
-heterocycles of neighboring complexes resulting in dimeric structures. The homoleptic complexes show a different behavior.
Homoleptic and heteroleptic gold(
i
) complexes ligated by phosphines with
N
-heterocycles in the periphery were prepared.</abstract><doi>10.1039/c3dt52893f</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_rsc_primary_c3dt52893f |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Gold(i) complexes with heteroaryl phosphine ligandsElectronic supplementary information (ESI) available. CCDC 960836-960840. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3dt52893f |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-12T23%3A13%3A12IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-rsc&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Gold(i)%20complexes%20with%20heteroaryl%20phosphine%20ligandsElectronic%20supplementary%20information%20(ESI)%20available.%20CCDC%20960836-960840.%20For%20ESI%20and%20crystallographic%20data%20in%20CIF%20or%20other%20electronic%20format%20see%20DOI:%2010.1039/c3dt52893f&rft.au=Sarcher,%20Christian&rft.date=2014-01-14&rft.volume=43&rft.issue=6&rft.spage=2397&rft.epage=245&rft.pages=2397-245&rft.issn=1477-9226&rft.eissn=1477-9234&rft_id=info:doi/10.1039/c3dt52893f&rft_dat=%3Crsc%3Ec3dt52893f%3C/rsc%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |