Structural diversity and spectral and thermal properties of the first alkaline earth metal tetracyanidoborates: [Mg(H2O)6][B(CN)4]2, [Mg(H2O)2][B(CN)4]2, [Mg(DMF)6][B(CN)4]2, [Ca(H2O)3][B(CN)4]2, and [Ca(H2O)2(CH3CN)][B(CN)4]2CCDC 893429, 705243-705245, 884526 and 893430. For crystallographic data in CIF or other electronic format see DOI: 10.1039/c3dt51945g

The first members of tetracyanidoborate salts with alkaline earth cations, [Mg(H 2 O) 6 ][B(CN) 4 ] 2 ( 1 ), [Mg(H 2 O) 2 ][B(CN) 4 ] 2 ( 2 ), [Mg(DMF) 6 ][B(CN) 4 ] 2 ( 3 ), [Ca(H 2 O) 3 ][B(CN) 4 ] 2 ( 4 ), and [Ca(H 2 O) 2 (CH 3 CN)][B(CN) 4 ] 2 ( 5 ), were synthesized. Their structures, obtained...

Ausführliche Beschreibung

Bibliographische Detailangaben

Hauptverfasser:	Nitschke, Christian, Köckerling, Martin, Bernhardt, Eduard, Küppers, Torsten, Willner, Helge
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!