Synthesis and crystal structure of Fe6Ca2(SeO3)9Cl4 a porous oxohalideElectronic supplementary information (ESI) available: Experimental details, crystal structure refinement parameters, bond valence sum (BVS) calculations, EDS-analysis data, sorption isotherms, PXRD-data. See DOI: 10.1039/c3dt50952d
A porous oxohalide, Fe 6 Ca 2 (SeO 3 ) 9 Cl 4 , has been synthesized by solid state reactions using concentrated HCl as the Cl-source. It crystallizes in the hexagonal space group P 6 3 / m with unit cell parameters a = 12.118(2) , c = 12.703(4) , Z = 2. The crystal structure is an open framework ha...
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| creator | Hu, Shichao Johnsson, Mats |
| description | A porous oxohalide, Fe
6
Ca
2
(SeO
3
)
9
Cl
4
, has been synthesized by solid state reactions using concentrated HCl as the Cl-source. It crystallizes in the hexagonal space group
P
6
3
/
m
with unit cell parameters
a
= 12.118(2) ,
c
= 12.703(4) ,
Z
= 2. The crystal structure is an open framework having one-dimensional channels extending along [001] that the chlorine atoms and lone pairs on Se
4+
are facing. The channels in this framework structure are unusually large compared to other oxohalide compounds and also accessible to guest molecules. Water vapor sorption measurements show an uptake of 9 wt% at 293 K.
A new porous oxohalide, Fe
6
Ca
2
(SeO
3
)
9
Cl
4
, is synthesized and characterized. The compound can be described as an open 3D framework where the Cl
and the lone-pairs on Se
4+
are facing the channels, which are unusually large for an oxohalide, with a diameter of 6.4 . |
| doi_str_mv | 10.1039/c3dt50952d |
| format | Article |
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6
Ca
2
(SeO
3
)
9
Cl
4
, has been synthesized by solid state reactions using concentrated HCl as the Cl-source. It crystallizes in the hexagonal space group
P
6
3
/
m
with unit cell parameters
a
= 12.118(2) ,
c
= 12.703(4) ,
Z
= 2. The crystal structure is an open framework having one-dimensional channels extending along [001] that the chlorine atoms and lone pairs on Se
4+
are facing. The channels in this framework structure are unusually large compared to other oxohalide compounds and also accessible to guest molecules. Water vapor sorption measurements show an uptake of 9 wt% at 293 K.
A new porous oxohalide, Fe
6
Ca
2
(SeO
3
)
9
Cl
4
, is synthesized and characterized. The compound can be described as an open 3D framework where the Cl
and the lone-pairs on Se
4+
are facing the channels, which are unusually large for an oxohalide, with a diameter of 6.4 .</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c3dt50952d</identifier><language>eng</language><creationdate>2013-05</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Hu, Shichao</creatorcontrib><creatorcontrib>Johnsson, Mats</creatorcontrib><title>Synthesis and crystal structure of Fe6Ca2(SeO3)9Cl4 a porous oxohalideElectronic supplementary information (ESI) available: Experimental details, crystal structure refinement parameters, bond valence sum (BVS) calculations, EDS-analysis data, sorption isotherms, PXRD-data. See DOI: 10.1039/c3dt50952d</title><description>A porous oxohalide, Fe
6
Ca
2
(SeO
3
)
9
Cl
4
, has been synthesized by solid state reactions using concentrated HCl as the Cl-source. It crystallizes in the hexagonal space group
P
6
3
/
m
with unit cell parameters
a
= 12.118(2) ,
c
= 12.703(4) ,
Z
= 2. The crystal structure is an open framework having one-dimensional channels extending along [001] that the chlorine atoms and lone pairs on Se
4+
are facing. The channels in this framework structure are unusually large compared to other oxohalide compounds and also accessible to guest molecules. Water vapor sorption measurements show an uptake of 9 wt% at 293 K.
A new porous oxohalide, Fe
6
Ca
2
(SeO
3
)
9
Cl
4
, is synthesized and characterized. The compound can be described as an open 3D framework where the Cl
and the lone-pairs on Se
4+
are facing the channels, which are unusually large for an oxohalide, with a diameter of 6.4 .</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFkM1Lw0AQxaMo-HnxLoy3FpqaJv0gPdqm2FPFiHgr082Ermx2l91Naf57t0H0oOhpBt6Pee9NENwMov4gStJ7lhRuFKWjuDgOzgfDySRM42R48rXH47Pgwtr3KIrjaBSfH4V5I92WLLeAsgBmGutQgHWmZq42BKqEBY1nGHdyWiXddCaGgKCVUbUFtVdbFLygTBBzRknOwNZaC6pIOjQNcFkqU6HjSkIny5ddwB1ygRtBU8j2mgxvUQEFOS_Y3i8ZDJVctidBo8GKHBkPbpRPvENBkpG3raDz8Jp3gaFgtWgtPZTN8xAliuZQsUCHPbDK6DYQt8p3N5XHnt6e5-FB7kNOBPPVcgo_n3oVnJYoLF1_zsvgdpG9zB5DY9la-yq-8vobT_7X7_7S17ookw9D15jV</recordid><startdate>20130514</startdate><enddate>20130514</enddate><creator>Hu, Shichao</creator><creator>Johnsson, Mats</creator><scope/></search><sort><creationdate>20130514</creationdate><title>Synthesis and crystal structure of Fe6Ca2(SeO3)9Cl4 a porous oxohalideElectronic supplementary information (ESI) available: Experimental details, crystal structure refinement parameters, bond valence sum (BVS) calculations, EDS-analysis data, sorption isotherms, PXRD-data. See DOI: 10.1039/c3dt50952d</title><author>Hu, Shichao ; Johnsson, Mats</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c3dt50952d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hu, Shichao</creatorcontrib><creatorcontrib>Johnsson, Mats</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hu, Shichao</au><au>Johnsson, Mats</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and crystal structure of Fe6Ca2(SeO3)9Cl4 a porous oxohalideElectronic supplementary information (ESI) available: Experimental details, crystal structure refinement parameters, bond valence sum (BVS) calculations, EDS-analysis data, sorption isotherms, PXRD-data. See DOI: 10.1039/c3dt50952d</atitle><date>2013-05-14</date><risdate>2013</risdate><volume>42</volume><issue>22</issue><spage>7859</spage><epage>7862</epage><pages>7859-7862</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>A porous oxohalide, Fe
6
Ca
2
(SeO
3
)
9
Cl
4
, has been synthesized by solid state reactions using concentrated HCl as the Cl-source. It crystallizes in the hexagonal space group
P
6
3
/
m
with unit cell parameters
a
= 12.118(2) ,
c
= 12.703(4) ,
Z
= 2. The crystal structure is an open framework having one-dimensional channels extending along [001] that the chlorine atoms and lone pairs on Se
4+
are facing. The channels in this framework structure are unusually large compared to other oxohalide compounds and also accessible to guest molecules. Water vapor sorption measurements show an uptake of 9 wt% at 293 K.
A new porous oxohalide, Fe
6
Ca
2
(SeO
3
)
9
Cl
4
, is synthesized and characterized. The compound can be described as an open 3D framework where the Cl
and the lone-pairs on Se
4+
are facing the channels, which are unusually large for an oxohalide, with a diameter of 6.4 .</abstract><doi>10.1039/c3dt50952d</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
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| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_rsc_primary_c3dt50952d |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| title | Synthesis and crystal structure of Fe6Ca2(SeO3)9Cl4 a porous oxohalideElectronic supplementary information (ESI) available: Experimental details, crystal structure refinement parameters, bond valence sum (BVS) calculations, EDS-analysis data, sorption isotherms, PXRD-data. See DOI: 10.1039/c3dt50952d |
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