Pentacoordinate silicon complexes with dynamic motion resembling a pendulum on the SN2 reaction pathwayElectronic supplementary information (ESI) available. CCDC 927438927443. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3dt50613d
A series of glutarimide derivatives which has two carbonyl coordination sites for intramolecular pentacoordination at silicon with a X 1+ n SiC 3 n O moiety have been synthesised and characterized. The substituent (leaving group) effects on the SiO bond exchange between the two coordination sites (r...
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