Facile synthesis of the new tripodal tetraamine ligand tris(thiazolylmethyl) amine, and full characterization of two ferrous complexesElectronic supplementary information (ESI) available: Synthetic details for the preparation of the ligand and complexes. All spectroscopic and analytical data relevant to the characterization of the complexes. CCDC 907958 [(TTA)FeCl2] and 907959 [(TTA)Fe(OTf)2]. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3dt50484k
We report in this communication the facile synthesis of the new tris(thiazolylmethyl)amine TTA ligand and the full characterization in solution and in the solid state of two ferrous complexes, [(TTA)FeCl 2 ] and [(TTA)Fe(OTf) 2 ]. TTA, the first example of a simple tris(thiazolemethyl)amine chelate...
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| creator | Thibon, Aurore Karmazin-Brelot, Lydia Mandon, Dominique |
| description | We report in this communication the facile synthesis of the new tris(thiazolylmethyl)amine TTA ligand and the full characterization in solution and in the solid state of two ferrous complexes, [(TTA)FeCl
2
] and [(TTA)Fe(OTf)
2
]. TTA, the first example of a simple tris(thiazolemethyl)amine chelate - the second one only within this class of tripods - exerts a weak ligand field and the tertiary amine is weakly bound to the metal centre.
The new TTA ligand has been synthesized and the full characterization of the high-spin [(TTA)FeCl
2
] and [(TTA)Fe(OTf)
2
] complexes is reported. |
| doi_str_mv | 10.1039/c3dt50484k |
| format | Article |
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2
] and [(TTA)Fe(OTf)
2
]. TTA, the first example of a simple tris(thiazolemethyl)amine chelate - the second one only within this class of tripods - exerts a weak ligand field and the tertiary amine is weakly bound to the metal centre.
The new TTA ligand has been synthesized and the full characterization of the high-spin [(TTA)FeCl
2
] and [(TTA)Fe(OTf)
2
] complexes is reported.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c3dt50484k</identifier><language>eng</language><creationdate>2013-04</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Thibon, Aurore</creatorcontrib><creatorcontrib>Karmazin-Brelot, Lydia</creatorcontrib><creatorcontrib>Mandon, Dominique</creatorcontrib><title>Facile synthesis of the new tripodal tetraamine ligand tris(thiazolylmethyl) amine, and full characterization of two ferrous complexesElectronic supplementary information (ESI) available: Synthetic details for the preparation of the ligand and complexes. All spectroscopic and analytical data relevant to the characterization of the complexes. CCDC 907958 [(TTA)FeCl2] and 907959 [(TTA)Fe(OTf)2]. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3dt50484k</title><description>We report in this communication the facile synthesis of the new tris(thiazolylmethyl)amine TTA ligand and the full characterization in solution and in the solid state of two ferrous complexes, [(TTA)FeCl
2
] and [(TTA)Fe(OTf)
2
]. TTA, the first example of a simple tris(thiazolemethyl)amine chelate - the second one only within this class of tripods - exerts a weak ligand field and the tertiary amine is weakly bound to the metal centre.
The new TTA ligand has been synthesized and the full characterization of the high-spin [(TTA)FeCl
2
] and [(TTA)Fe(OTf)
2
] complexes is reported.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFUsFO20AQNahIpS0X7pWGWyJB6thJg7khE6s5cSC3CkXT9RhvO95d7W4A8818RNcOcg6t2sNqR2_evvdmtFF0Oo0n0zjNvoi09PN4djn7dRgdT2eLxUWWpLN3Q518fR99cO5nHCdJPE-OD14LFJIJXKt8TU460BWEChQ9gbfS6BIZPHmL2EhFwPIBVdm13MjXEl80t9yQr1seQ085h45QbZlB1GhReLLyBb3Uqhd_0lCRtXrrQOjGMD2TWzIJb7WSAtzWBKwh5dG2IFWlbbN7PFrerYLHI0rGH0xXcNeH9uFRST6gDgK5T28smWA9eNZD8O4MthO4Dimd6c2d0CZI7UjIbdANo5foESwxPaLy4HWv9de5OnwvnOc3OWTxIptfwvfRen09Lijn5L7X7_FswEe362qc3E-gCPHDkLuQtnUemfWDRVN3M3ZJpIJ8VUDg6WBogfaL2y0KHBHc3K6u4M8_8Sk6qpAdnbzdH6PPxXKdf7uwTmyMlU3Y-GZPT__fP_tXf2PKKv0Ndt3c2A</recordid><startdate>20130423</startdate><enddate>20130423</enddate><creator>Thibon, Aurore</creator><creator>Karmazin-Brelot, Lydia</creator><creator>Mandon, Dominique</creator><scope/></search><sort><creationdate>20130423</creationdate><title>Facile synthesis of the new tripodal tetraamine ligand tris(thiazolylmethyl) amine, and full characterization of two ferrous complexesElectronic supplementary information (ESI) available: Synthetic details for the preparation of the ligand and complexes. All spectroscopic and analytical data relevant to the characterization of the complexes. CCDC 907958 [(TTA)FeCl2] and 907959 [(TTA)Fe(OTf)2]. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3dt50484k</title><author>Thibon, Aurore ; Karmazin-Brelot, Lydia ; Mandon, Dominique</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c3dt50484k3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Thibon, Aurore</creatorcontrib><creatorcontrib>Karmazin-Brelot, Lydia</creatorcontrib><creatorcontrib>Mandon, Dominique</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Thibon, Aurore</au><au>Karmazin-Brelot, Lydia</au><au>Mandon, Dominique</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Facile synthesis of the new tripodal tetraamine ligand tris(thiazolylmethyl) amine, and full characterization of two ferrous complexesElectronic supplementary information (ESI) available: Synthetic details for the preparation of the ligand and complexes. All spectroscopic and analytical data relevant to the characterization of the complexes. CCDC 907958 [(TTA)FeCl2] and 907959 [(TTA)Fe(OTf)2]. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3dt50484k</atitle><date>2013-04-23</date><risdate>2013</risdate><volume>42</volume><issue>19</issue><spage>675</spage><epage>677</epage><pages>675-677</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>We report in this communication the facile synthesis of the new tris(thiazolylmethyl)amine TTA ligand and the full characterization in solution and in the solid state of two ferrous complexes, [(TTA)FeCl
2
] and [(TTA)Fe(OTf)
2
]. TTA, the first example of a simple tris(thiazolemethyl)amine chelate - the second one only within this class of tripods - exerts a weak ligand field and the tertiary amine is weakly bound to the metal centre.
The new TTA ligand has been synthesized and the full characterization of the high-spin [(TTA)FeCl
2
] and [(TTA)Fe(OTf)
2
] complexes is reported.</abstract><doi>10.1039/c3dt50484k</doi><tpages>3</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Facile synthesis of the new tripodal tetraamine ligand tris(thiazolylmethyl) amine, and full characterization of two ferrous complexesElectronic supplementary information (ESI) available: Synthetic details for the preparation of the ligand and complexes. All spectroscopic and analytical data relevant to the characterization of the complexes. CCDC 907958 [(TTA)FeCl2] and 907959 [(TTA)Fe(OTf)2]. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3dt50484k |
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