Enhanced ultraviolet responses in thin-film InGaP solar cells by down-shifting
Layers of poly(methyl methacrylate) doped with the Eu complex Eu(DPEPO)(hfac) 3 (EuDH) provide a means for down-shifting incident ultraviolet (UV) light into the visible range, with beneficial effects on the performance of solar cells, as demonstrated with thin-film InGaP devices formed by epitaxial...
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Veröffentlicht in: | Phys. Chem. Chem. Phys 2013-12, Vol.15 (47), p.2434-2437 |
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creator | Sheng, Xing Corcoran, Christopher J He, Junwen Shen, Ling Kim, Seungho Park, Jongwook Nuzzo, Ralph G Rogers, John A |
description | Layers of poly(methyl methacrylate) doped with the Eu complex Eu(DPEPO)(hfac)
3
(EuDH) provide a means for down-shifting incident ultraviolet (UV) light into the visible range, with beneficial effects on the performance of solar cells, as demonstrated with thin-film InGaP devices formed by epitaxial liftoff. Experimental and computational results establish important aspects of gain and loss mechanisms in the UV range. Measurements show that InGaP cells with coatings of EuDH doped PMMA exhibit enhanced currents (8.68 mA cm
−2
) and power conversion efficiencies (9.48%), both due to increased responses at wavelengths between 300-360 nm.
A luminescent Eu complex (EuDH) doped PMMA is coated on thin-film InGaP solar cells, for the demonstration of enhanced ultraviolet (UV) responses. |
doi_str_mv | 10.1039/c3cp54096k |
format | Article |
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3
(EuDH) provide a means for down-shifting incident ultraviolet (UV) light into the visible range, with beneficial effects on the performance of solar cells, as demonstrated with thin-film InGaP devices formed by epitaxial liftoff. Experimental and computational results establish important aspects of gain and loss mechanisms in the UV range. Measurements show that InGaP cells with coatings of EuDH doped PMMA exhibit enhanced currents (8.68 mA cm
−2
) and power conversion efficiencies (9.48%), both due to increased responses at wavelengths between 300-360 nm.
A luminescent Eu complex (EuDH) doped PMMA is coated on thin-film InGaP solar cells, for the demonstration of enhanced ultraviolet (UV) responses.</description><identifier>ISSN: 1463-9076</identifier><identifier>EISSN: 1463-9084</identifier><identifier>DOI: 10.1039/c3cp54096k</identifier><identifier>PMID: 24113691</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Chemistry ; Energy conversion efficiency ; Exact sciences and technology ; Gain ; General and physical chemistry ; Liftoff ; Photovoltaic cells ; Polymethyl methacrylates ; solar (photovoltaic), solid state lighting, phonons, thermal conductivity, electrodes - solar, materials and chemistry by design, optics, synthesis (novel materials), synthesis (self-assembly) ; Solar cells ; Thin films ; Ultraviolet ; Wavelengths</subject><ispartof>Phys. Chem. Chem. Phys, 2013-12, Vol.15 (47), p.2434-2437</ispartof><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c425t-4394a4ea7fc16f95bcbf66d401a214c453421789269d244bfaaf609c901e67c83</citedby><cites>FETCH-LOGICAL-c425t-4394a4ea7fc16f95bcbf66d401a214c453421789269d244bfaaf609c901e67c83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,881,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27960935$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24113691$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/1160667$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Sheng, Xing</creatorcontrib><creatorcontrib>Corcoran, Christopher J</creatorcontrib><creatorcontrib>He, Junwen</creatorcontrib><creatorcontrib>Shen, Ling</creatorcontrib><creatorcontrib>Kim, Seungho</creatorcontrib><creatorcontrib>Park, Jongwook</creatorcontrib><creatorcontrib>Nuzzo, Ralph G</creatorcontrib><creatorcontrib>Rogers, John A</creatorcontrib><creatorcontrib>Energy Frontier Research Centers (EFRC)</creatorcontrib><creatorcontrib>Light-Material Interactions in Energy Conversion (LMI)</creatorcontrib><title>Enhanced ultraviolet responses in thin-film InGaP solar cells by down-shifting</title><title>Phys. Chem. Chem. Phys</title><addtitle>Phys Chem Chem Phys</addtitle><description>Layers of poly(methyl methacrylate) doped with the Eu complex Eu(DPEPO)(hfac)
3
(EuDH) provide a means for down-shifting incident ultraviolet (UV) light into the visible range, with beneficial effects on the performance of solar cells, as demonstrated with thin-film InGaP devices formed by epitaxial liftoff. Experimental and computational results establish important aspects of gain and loss mechanisms in the UV range. Measurements show that InGaP cells with coatings of EuDH doped PMMA exhibit enhanced currents (8.68 mA cm
−2
) and power conversion efficiencies (9.48%), both due to increased responses at wavelengths between 300-360 nm.
A luminescent Eu complex (EuDH) doped PMMA is coated on thin-film InGaP solar cells, for the demonstration of enhanced ultraviolet (UV) responses.</description><subject>Chemistry</subject><subject>Energy conversion efficiency</subject><subject>Exact sciences and technology</subject><subject>Gain</subject><subject>General and physical chemistry</subject><subject>Liftoff</subject><subject>Photovoltaic cells</subject><subject>Polymethyl methacrylates</subject><subject>solar (photovoltaic), solid state lighting, phonons, thermal conductivity, electrodes - solar, materials and chemistry by design, optics, synthesis (novel materials), synthesis (self-assembly)</subject><subject>Solar cells</subject><subject>Thin films</subject><subject>Ultraviolet</subject><subject>Wavelengths</subject><issn>1463-9076</issn><issn>1463-9084</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqN0c9rFDEUB_Agiq3Vi3clCoIIo3mTH7M5Sqm1UNSDnkMmk7jR2WSal1X635uy6-5NPOVBPrwffAl5CuwtMK7fOe4WKZhWP--RUxCKd5qtxP1DPagT8gjxB2MMJPCH5KQXAFxpOCWfLtLaJucnup1rsb9inn2lxeOSE3qkMdG6jqkLcd7Qq3Rpv1DMsy3U-XlGOt7SKf9OHa5jqDF9f0weBDujf7J_z8i3Dxdfzz92158vr87fX3dO9LJ2gmthhbdDcKCClqMbg1KTYGB7EE5ILnoYVrpXeuqFGIO1QTHtNAOvBrfiZ-Tlrm_GGg26WL1bu5ySd9UAKKbU0NDrHVpKvtl6rGYT8W5vm3zeogExSNmo0P9BpQYpB80bfbOjrmTE4oNZStzYcmuAmbs8zDGPhp_v-27HjZ8O9G8ADbzaA4vOzqG0MCIe3aDb3Vw292LnCrrD73GQWabQzLN_Gf4HwZKmbg</recordid><startdate>20131221</startdate><enddate>20131221</enddate><creator>Sheng, Xing</creator><creator>Corcoran, Christopher J</creator><creator>He, Junwen</creator><creator>Shen, Ling</creator><creator>Kim, Seungho</creator><creator>Park, Jongwook</creator><creator>Nuzzo, Ralph G</creator><creator>Rogers, John A</creator><general>Royal Society of Chemistry</general><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7QQ</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>OTOTI</scope></search><sort><creationdate>20131221</creationdate><title>Enhanced ultraviolet responses in thin-film InGaP solar cells by down-shifting</title><author>Sheng, Xing ; Corcoran, Christopher J ; He, Junwen ; Shen, Ling ; Kim, Seungho ; Park, Jongwook ; Nuzzo, Ralph G ; Rogers, John A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c425t-4394a4ea7fc16f95bcbf66d401a214c453421789269d244bfaaf609c901e67c83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Chemistry</topic><topic>Energy conversion efficiency</topic><topic>Exact sciences and technology</topic><topic>Gain</topic><topic>General and physical chemistry</topic><topic>Liftoff</topic><topic>Photovoltaic cells</topic><topic>Polymethyl methacrylates</topic><topic>solar (photovoltaic), solid state lighting, phonons, thermal conductivity, electrodes - solar, materials and chemistry by design, optics, synthesis (novel materials), synthesis (self-assembly)</topic><topic>Solar cells</topic><topic>Thin films</topic><topic>Ultraviolet</topic><topic>Wavelengths</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sheng, Xing</creatorcontrib><creatorcontrib>Corcoran, Christopher J</creatorcontrib><creatorcontrib>He, Junwen</creatorcontrib><creatorcontrib>Shen, Ling</creatorcontrib><creatorcontrib>Kim, Seungho</creatorcontrib><creatorcontrib>Park, Jongwook</creatorcontrib><creatorcontrib>Nuzzo, Ralph G</creatorcontrib><creatorcontrib>Rogers, John A</creatorcontrib><creatorcontrib>Energy Frontier Research Centers (EFRC)</creatorcontrib><creatorcontrib>Light-Material Interactions in Energy Conversion (LMI)</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Ceramic Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>OSTI.GOV</collection><jtitle>Phys. Chem. Chem. Phys</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sheng, Xing</au><au>Corcoran, Christopher J</au><au>He, Junwen</au><au>Shen, Ling</au><au>Kim, Seungho</au><au>Park, Jongwook</au><au>Nuzzo, Ralph G</au><au>Rogers, John A</au><aucorp>Energy Frontier Research Centers (EFRC)</aucorp><aucorp>Light-Material Interactions in Energy Conversion (LMI)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhanced ultraviolet responses in thin-film InGaP solar cells by down-shifting</atitle><jtitle>Phys. Chem. Chem. Phys</jtitle><addtitle>Phys Chem Chem Phys</addtitle><date>2013-12-21</date><risdate>2013</risdate><volume>15</volume><issue>47</issue><spage>2434</spage><epage>2437</epage><pages>2434-2437</pages><issn>1463-9076</issn><eissn>1463-9084</eissn><abstract>Layers of poly(methyl methacrylate) doped with the Eu complex Eu(DPEPO)(hfac)
3
(EuDH) provide a means for down-shifting incident ultraviolet (UV) light into the visible range, with beneficial effects on the performance of solar cells, as demonstrated with thin-film InGaP devices formed by epitaxial liftoff. Experimental and computational results establish important aspects of gain and loss mechanisms in the UV range. Measurements show that InGaP cells with coatings of EuDH doped PMMA exhibit enhanced currents (8.68 mA cm
−2
) and power conversion efficiencies (9.48%), both due to increased responses at wavelengths between 300-360 nm.
A luminescent Eu complex (EuDH) doped PMMA is coated on thin-film InGaP solar cells, for the demonstration of enhanced ultraviolet (UV) responses.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><pmid>24113691</pmid><doi>10.1039/c3cp54096k</doi><tpages>4</tpages></addata></record> |
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source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Chemistry Energy conversion efficiency Exact sciences and technology Gain General and physical chemistry Liftoff Photovoltaic cells Polymethyl methacrylates solar (photovoltaic), solid state lighting, phonons, thermal conductivity, electrodes - solar, materials and chemistry by design, optics, synthesis (novel materials), synthesis (self-assembly) Solar cells Thin films Ultraviolet Wavelengths |
title | Enhanced ultraviolet responses in thin-film InGaP solar cells by down-shifting |
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