Enhanced ultraviolet responses in thin-film InGaP solar cells by down-shifting

Layers of poly(methyl methacrylate) doped with the Eu complex Eu(DPEPO)(hfac) 3 (EuDH) provide a means for down-shifting incident ultraviolet (UV) light into the visible range, with beneficial effects on the performance of solar cells, as demonstrated with thin-film InGaP devices formed by epitaxial...

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Veröffentlicht in:Phys. Chem. Chem. Phys 2013-12, Vol.15 (47), p.2434-2437
Hauptverfasser: Sheng, Xing, Corcoran, Christopher J, He, Junwen, Shen, Ling, Kim, Seungho, Park, Jongwook, Nuzzo, Ralph G, Rogers, John A
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container_end_page 2437
container_issue 47
container_start_page 2434
container_title Phys. Chem. Chem. Phys
container_volume 15
creator Sheng, Xing
Corcoran, Christopher J
He, Junwen
Shen, Ling
Kim, Seungho
Park, Jongwook
Nuzzo, Ralph G
Rogers, John A
description Layers of poly(methyl methacrylate) doped with the Eu complex Eu(DPEPO)(hfac) 3 (EuDH) provide a means for down-shifting incident ultraviolet (UV) light into the visible range, with beneficial effects on the performance of solar cells, as demonstrated with thin-film InGaP devices formed by epitaxial liftoff. Experimental and computational results establish important aspects of gain and loss mechanisms in the UV range. Measurements show that InGaP cells with coatings of EuDH doped PMMA exhibit enhanced currents (8.68 mA cm −2 ) and power conversion efficiencies (9.48%), both due to increased responses at wavelengths between 300-360 nm. A luminescent Eu complex (EuDH) doped PMMA is coated on thin-film InGaP solar cells, for the demonstration of enhanced ultraviolet (UV) responses.
doi_str_mv 10.1039/c3cp54096k
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Chemistry
Energy conversion efficiency
Exact sciences and technology
Gain
General and physical chemistry
Liftoff
Photovoltaic cells
Polymethyl methacrylates
solar (photovoltaic), solid state lighting, phonons, thermal conductivity, electrodes - solar, materials and chemistry by design, optics, synthesis (novel materials), synthesis (self-assembly)
Solar cells
Thin films
Ultraviolet
Wavelengths
title Enhanced ultraviolet responses in thin-film InGaP solar cells by down-shifting
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