Rational design, characterization and catalytic application of metal clusters functionalized with hydrophilic, chiral ligands: a proof of principle studyElectronic supplementary information (ESI) available: Particle size analyses of "unprotected" and CYS-functionalized clusters, representive TEM images of NAC- and GLU-clusters, representive HPLC chromatographs, and a table showing the ligand coverages. See DOI: 10.1039/c3cp53626b
A proof of principle is presented for the rational design of metal clusters functionalized with hydrophilic, chiral ligands. A colloidal method is used to prepare "unprotected" metal clusters of well-defined size that are subsequently functionalized in a separate step with hydrophilic, chi...
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