Oxidation of 2-amino-substituted BODIPYs providing pyrazine-fused BODIPY trimersElectronic supplementary information (ESI) available: Experimental details for 4a and 4b, the summary of the electrochemical investigation and X-ray crystallographic data for 4a and 4b. CCDC 971649 and 971650. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3cc48738e
Oxidation of 2-amino-substituted BODIPYs afforded BODIPY trimers in a one-step operation. The trimer consists of a pyrazine-fused BODIPY dimer to which one BODIPY unit is connected through an NH linkage. Effective expansion of π-conjugation over the fused dimer was observed in optical and electroche...
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