A twisted bi-icosahedral Au25 cluster enclosed by bulky arenethiolatesElectronic supplementary information (ESI) available: Details of synthesis and characterization, measurements, and analysis. See DOI: 10.1039/c3cc47154c
Ligation of 2,6-diphenylbenzenethiol (DppSH) onto Au clusters stabilized by poly( N -vinyl-2-pyrrolidone) and subsequent core etching yielded a single cluster Au 25 (SDpp) 11 . High-energy X-ray diffraction measurement showed that Au 25 constitutes a core in Au 25 (SDpp) 11 . We propose a bi-icosahe...
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