A modular total synthesis of (±)-trigonoliimine CElectronic supplementary information (ESI) available: Characterization data and spectra of new compounds. See DOI: 10.1039/c3cc45512b

A convergent total synthesis of trigonoliimine C has been executed by employing three catalytic transformations in sequence. The key reactions that have been developed in this context include the [Au]-catalyzed addition of protected tryptamine to isatogens and the reduction of N-OH to NH with hydraz...

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Hauptverfasser: Narendraprasad Reddy, B, Ramana, Chepuri V
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description A convergent total synthesis of trigonoliimine C has been executed by employing three catalytic transformations in sequence. The key reactions that have been developed in this context include the [Au]-catalyzed addition of protected tryptamine to isatogens and the reduction of N-OH to NH with hydrazine monohydrate. Trigonoliimine C and its analogues have been assembled from simple building blocks by employing three [metal]-catalysed reactions in sequence involving the synthesis of the pentacyclic core.
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title A modular total synthesis of (±)-trigonoliimine CElectronic supplementary information (ESI) available: Characterization data and spectra of new compounds. See DOI: 10.1039/c3cc45512b
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