Preorganized assembly of three iron(ii) or manganese(ii) -diketiminate complexes using a cyclophane ligandElectronic supplementary information (ESI) available: Full experimental procedures, spectroscopic data, cyclic voltammetry, and crystallographic data. CCDC 923619923621. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3cc43395a

A trinucleating cyclophane bearing three -diketimine arms, and the corresponding iron( ii ) and manganese( ii ) complexes have been synthesized and characterized. The three metal ions are oriented towards the internal void space, and are coordinated by a N 2 Br 2 donor set, in which a unique combina...

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Hauptverfasser: Guillet, Gary L, Sloane, Forrest T, Ermert, David M, Calkins, Matthew W, Peprah, Marcus K, Knowles, Elisabeth S, imr, Erik, Abboud, Khalil A, Meisel, Mark W, Murray, Leslie J
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Sprache:eng
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