Catalytic platinum-initiated cation-olefin reactions with alkene terminating groupsElectronic supplementary information (ESI) available: Synthesis and characterization of all compounds. See DOI: 10.1039/c3cc41699b
A series of phosphinePt 2+ -catalysts is reported, which enable the oxidative cascade cyclization of poly-alkene substrates. When the terminus is appropriately arranged and a catalyst reoxidation mediator is included, several polycyclic all carbon skeletons can be obtained. In one example, a chiral...
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| creator | Sokol, Joseph G Cochrane, Nikki A Becker, Jennifer J Gagn, Michel R |
| description | A series of phosphinePt
2+
-catalysts is reported, which enable the oxidative cascade cyclization of poly-alkene substrates. When the terminus is appropriately arranged and a catalyst reoxidation mediator is included, several polycyclic all carbon skeletons can be obtained. In one example, a chiral P
2
Pt
+2
catalyst provides up to 79% ee.
A series of phosphinePt
2+
-catalysts is reported, which enable the oxidative cascade cyclization of poly-alkene substrates. |
| doi_str_mv | 10.1039/c3cc41699b |
| format | Article |
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2+
-catalysts is reported, which enable the oxidative cascade cyclization of poly-alkene substrates. When the terminus is appropriately arranged and a catalyst reoxidation mediator is included, several polycyclic all carbon skeletons can be obtained. In one example, a chiral P
2
Pt
+2
catalyst provides up to 79% ee.
A series of phosphinePt
2+
-catalysts is reported, which enable the oxidative cascade cyclization of poly-alkene substrates.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c3cc41699b</identifier><language>eng</language><creationdate>2013-05</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Sokol, Joseph G</creatorcontrib><creatorcontrib>Cochrane, Nikki A</creatorcontrib><creatorcontrib>Becker, Jennifer J</creatorcontrib><creatorcontrib>Gagn, Michel R</creatorcontrib><title>Catalytic platinum-initiated cation-olefin reactions with alkene terminating groupsElectronic supplementary information (ESI) available: Synthesis and characterization of all compounds. See DOI: 10.1039/c3cc41699b</title><description>A series of phosphinePt
2+
-catalysts is reported, which enable the oxidative cascade cyclization of poly-alkene substrates. When the terminus is appropriately arranged and a catalyst reoxidation mediator is included, several polycyclic all carbon skeletons can be obtained. In one example, a chiral P
2
Pt
+2
catalyst provides up to 79% ee.
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2+
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2+
-catalysts is reported, which enable the oxidative cascade cyclization of poly-alkene substrates. When the terminus is appropriately arranged and a catalyst reoxidation mediator is included, several polycyclic all carbon skeletons can be obtained. In one example, a chiral P
2
Pt
+2
catalyst provides up to 79% ee.
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2+
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Catalytic platinum-initiated cation-olefin reactions with alkene terminating groupsElectronic supplementary information (ESI) available: Synthesis and characterization of all compounds. See DOI: 10.1039/c3cc41699b |
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