Photochemical properties of multi-azobenzene compoundsElectronic supplementary information (ESI) available: Chemical syntheses of BPAPA and TPAPA, X-ray diffraction structure of TPAPA (cif file), tabulated results of excited-state calculations, 1H and 2D-HSQC NMR data for TPAPA. CCDC 897971. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2pp25291k
A systematic study is reported of the photochemical properties of the multi-azobenzene compounds bis[4-(phenylazo)phenyl]amine (BPAPA) and tris[4-(phenylazo)phenyl]amine (TPAPA) compared to the parent molecule 4-aminoazobenzene (AAB). The bis- and tris-azobenzenes were synthesised by a variant of th...
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