Luminescence of a novel Eu(diketonato)-epoxiphenanthroline complex and covalent coupling to peptides via the epoxigroupElectronic supplementary information (ESI) available: FTIR spectra of all compounds; ESI MS, 1H and 13C NMR spectra and signal assignments for Na2GluSH-phen; absorption and luminescence spectra of Mel-phen and Trigly-phen. See DOI: 10.1039/c2nj40505a
The application of rare earth complexes in several techniques and technologies requires their strong, i.e. preferably covalent, fixation to a substrate. The particularly useful luminescence properties of - readily available - rare earth β-diketonate complexes can widely be maintained on co-ligation...
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