Structure, photophysics, and photooxidation of crowded diethynyltetracenesElectronic supplementary information (ESI) available: kinetic data, crystallographic information, and solid-state emission. CCDC reference numbers 853371 and 853372. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2jm16173g
This paper describes a previously unreported class of sterically crowded tetracene derivatives that have both phenyl and ethynyl substituents. The steric crowding above and below the tetracene core prevents overlap between the extended -systems of the acenes. Substituent effects cause these tetra-su...
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