Characterization of nickel(ii)-acylperoxo species relevant to catalytic alkane hydroxylation by nickel complex with mCPBAElectronic supplementary information (ESI) available. See DOI: 10.1039/c2dt32419a
Nickel complexes with hydrotris(pyrazolyl)borate ( = Tp R ) ligands catalyze alkane oxidation with organic peroxide meta -Cl-C 6 H 4 C(&z.dbd;O)OOH ( = m CPBA). The electronic and steric hindrance properties of Tp R affect the catalyses. The complex with an electron-withdrawing group containing...
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