Copper complexes of the non-innocent β-diketiminate ligand containing phenol groupsElectronic supplementary information (ESI) available: ESI-MS of [CuII(L3−)]− and [CuII(L−)]+ (Fig. S1 and S5), ChemDraw structure of ligand SlaH2 (Fig. S2), cyclic voltammogram of (Et4N)[CuII(L3−)] (Fig. S3), 1H-NMR spectrum of [CuII(L&z.rad;2−)] (Fig. S4), DFT calculation results (Table S1, table S2 and Fig. 6), UV-vis spectra of the final reaction products (Fig. S7 and S8). CCDC 890157 and 890158. For ESI and cr

Copper complexes of the non-innocent β-diketiminate ligand containing phenol groupsElectronic supplementary information (ESI) available: ESI-MS of [CuII(L3−)]− and [CuII(L−)]+ (Fig. S1 and S5), ChemDraw structure of ligand SlaH2 (Fig. S2), cyclic voltammogram of (Et4N)[CuII(L3−)] (Fig. S3), 1H-NMR spectrum of [CuII(L&z.rad;2−)] (Fig. S4), DFT calculation results (Table S1, table S2 and Fig. 6), UV-vis spectra of the final reaction products (Fig. S7 and S8). CCDC 890157 and 890158. For ESI and cr

A new type of non-innocent β-diketiminate ligand having redox active phenol groups ( LH 3 , fully protonated form) has been developed, and the structure, physical properties and reactivity of the supported copper( ii ) complex [Cu II ( L 3− )] − ( L 3− , fully deprotonated tri-anionic form) as well...

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Hauptverfasser: Takaichi, June, Ohkubo, Kei, Sugimoto, Hideki, Nakano, Motohiro, Usa, Daisuke, Maekawa, Hiroaki, Fujieda, Nobutaka, Nishiwaki, Nagatoshi, Seki, Shu, Fukuzumi, Shunichi, Itoh, Shinobu
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