An α-Keggin polyoxometalate completely constructed from the late transition metal CoII as poly atomElectronic supplementary information (ESI) available: Details of synthesis, a typical procedure for styrene polymerization, Fig. S1-S16. CCDC 779511. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2dt31896b
We report a catalytic eight-cobalt-capped α-Keggin polyoxoazocobaltite with a highly symmetric structure completely constructed from the late transition-metal Co II as a poly atom, [Co 20 (OH) 24 (MMT) 12 (SO 4 )](NO 3 ) 2 ·6H 2 O ( 1 ) (MMT: 2-mercapto-5-methyl-1,3,4-thiadiazole). To the best of ou...
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| creator | Dong, Lanjun Li, Xiaofang Cao, Jie Chu, Wei Huang, Rudan |
| description | We report a catalytic eight-cobalt-capped α-Keggin polyoxoazocobaltite with a highly symmetric structure completely constructed from the late transition-metal Co
II
as a poly atom, [Co
20
(OH)
24
(MMT)
12
(SO
4
)](NO
3
)
2
·6H
2
O (
1
) (MMT: 2-mercapto-5-methyl-1,3,4-thiadiazole). To the best of our knowledge, this is the first homometallic Co
II
magnetic cluster bearing Keggin structure. It can serve as a potential catalyst in the styrene polymerization.
We report a catalytic eight-cobalt-capped α-Keggin polyoxoazocobaltite completely constructed from the late transition-metal Co
II
as a poly atom. |
| doi_str_mv | 10.1039/c2dt31896b |
| format | Article |
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II
as a poly atom, [Co
20
(OH)
24
(MMT)
12
(SO
4
)](NO
3
)
2
·6H
2
O (
1
) (MMT: 2-mercapto-5-methyl-1,3,4-thiadiazole). To the best of our knowledge, this is the first homometallic Co
II
magnetic cluster bearing Keggin structure. It can serve as a potential catalyst in the styrene polymerization.
We report a catalytic eight-cobalt-capped α-Keggin polyoxoazocobaltite completely constructed from the late transition-metal Co
II
as a poly atom.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c2dt31896b</identifier><language>eng</language><creationdate>2013-01</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Dong, Lanjun</creatorcontrib><creatorcontrib>Li, Xiaofang</creatorcontrib><creatorcontrib>Cao, Jie</creatorcontrib><creatorcontrib>Chu, Wei</creatorcontrib><creatorcontrib>Huang, Rudan</creatorcontrib><title>An α-Keggin polyoxometalate completely constructed from the late transition metal CoII as poly atomElectronic supplementary information (ESI) available: Details of synthesis, a typical procedure for styrene polymerization, Fig. S1-S16. CCDC 779511. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2dt31896b</title><description>We report a catalytic eight-cobalt-capped α-Keggin polyoxoazocobaltite with a highly symmetric structure completely constructed from the late transition-metal Co
II
as a poly atom, [Co
20
(OH)
24
(MMT)
12
(SO
4
)](NO
3
)
2
·6H
2
O (
1
) (MMT: 2-mercapto-5-methyl-1,3,4-thiadiazole). To the best of our knowledge, this is the first homometallic Co
II
magnetic cluster bearing Keggin structure. It can serve as a potential catalyst in the styrene polymerization.
We report a catalytic eight-cobalt-capped α-Keggin polyoxoazocobaltite completely constructed from the late transition-metal Co
II
as a poly atom.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFkTtPwzAUhQMCifJY2JEOG0htyKMP2g2lrYgYGMrCVLnOTWvk2JHtIsK_4o_wm7ACggEJJl_pnnO-YzsITuMojKN0fMWTwqXx9Xi42g06cX806o2TtL_3PSfDg-DQ2qcoSpJokHR2Hm8U3t96d7ReC4Vay0a_6Iock8wRuK5qSY5k40dlndlyRwVKoyu4DaEVOcOUFU5ohdaITOc5mG3TwJyuZpK4M1oJDrutfWJFyjHTQKhSm4q13ovZIr8Ee2ZCspWkCaY-TEgLXcI2yuOssF0wuKYW3GNqozkVW0PwIbCuMaSohVZkxGub2sVcrEMs4t4iHobIsmmG0Wg8iOMQc-_yTDBVgJvG-upSrw2rN75nwRzz9ZDlc3id9ngD-rnHZ29YIkzv8wl-f8BxsF8yaenk6zwKzuazh-y2Zyxf1kZU_gGWP_L0__35X_tlXZTpB-FcqFk</recordid><startdate>20130102</startdate><enddate>20130102</enddate><creator>Dong, Lanjun</creator><creator>Li, Xiaofang</creator><creator>Cao, Jie</creator><creator>Chu, Wei</creator><creator>Huang, Rudan</creator><scope/></search><sort><creationdate>20130102</creationdate><title>An α-Keggin polyoxometalate completely constructed from the late transition metal CoII as poly atomElectronic supplementary information (ESI) available: Details of synthesis, a typical procedure for styrene polymerization, Fig. S1-S16. CCDC 779511. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2dt31896b</title><author>Dong, Lanjun ; Li, Xiaofang ; Cao, Jie ; Chu, Wei ; Huang, Rudan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c2dt31896b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dong, Lanjun</creatorcontrib><creatorcontrib>Li, Xiaofang</creatorcontrib><creatorcontrib>Cao, Jie</creatorcontrib><creatorcontrib>Chu, Wei</creatorcontrib><creatorcontrib>Huang, Rudan</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dong, Lanjun</au><au>Li, Xiaofang</au><au>Cao, Jie</au><au>Chu, Wei</au><au>Huang, Rudan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An α-Keggin polyoxometalate completely constructed from the late transition metal CoII as poly atomElectronic supplementary information (ESI) available: Details of synthesis, a typical procedure for styrene polymerization, Fig. S1-S16. CCDC 779511. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2dt31896b</atitle><date>2013-01-02</date><risdate>2013</risdate><volume>42</volume><issue>5</issue><spage>1342</spage><epage>1345</epage><pages>1342-1345</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>We report a catalytic eight-cobalt-capped α-Keggin polyoxoazocobaltite with a highly symmetric structure completely constructed from the late transition-metal Co
II
as a poly atom, [Co
20
(OH)
24
(MMT)
12
(SO
4
)](NO
3
)
2
·6H
2
O (
1
) (MMT: 2-mercapto-5-methyl-1,3,4-thiadiazole). To the best of our knowledge, this is the first homometallic Co
II
magnetic cluster bearing Keggin structure. It can serve as a potential catalyst in the styrene polymerization.
We report a catalytic eight-cobalt-capped α-Keggin polyoxoazocobaltite completely constructed from the late transition-metal Co
II
as a poly atom.</abstract><doi>10.1039/c2dt31896b</doi><tpages>4</tpages></addata></record> |
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| language | eng |
| recordid | cdi_rsc_primary_c2dt31896b |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | An α-Keggin polyoxometalate completely constructed from the late transition metal CoII as poly atomElectronic supplementary information (ESI) available: Details of synthesis, a typical procedure for styrene polymerization, Fig. S1-S16. CCDC 779511. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2dt31896b |
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