Zn(ii), Cd(ii) and Cu(ii) complexes of 2,5-bis{N-(2,6-diisopropylphenyl)iminomethyl}pyrrole: synthesis, structures and their high catalytic activity for efficient cyclic carbonate synthesis.Electronic supplementary information (ESI) available: Crystallographic data and structures of complexes 3a, 3b, 5a and 5b, spectra of all complexes and cyclic carbonates. CCDC 874343 (3b), 885290 (5a) and CCDC 885291 (5b). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2

The syntheses of Zn( ii ), Cd( ii ) and Cu( ii ) complexes of 2,5-bis{ N -(2,6-diisopropylphenyl)iminomethyl}pyrrole (DIP 2 pyr)H 1 and their catalytic activities in CO 2 fixation are reported. The structures of these complexes were characterized by IR, 1 H, 13 C NMR and single crystal X-ray diffrac...

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Hauptverfasser: Vignesh Babu, Heeralal, Muralidharan, Krishnamurthi
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Sprache:eng
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