Ionic liquid mediated routes to polydentate oxygen-donor adducts of cerium(iii) bromideElectronic supplementary information (ESI) available: Full experimental data and X-ray data tables are provided. CCDC reference numbers 845795845798. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2dt12333a
The preparation of a series of CeBr 3 molecular adducts supported by the polydentate oxygen donor ligands diglyme, dimethoxyethane and tetraglyme is reported. The new complexes are characterized structurally by X-ray diffraction and optically by photoluminescence studies. Dissolution of CeBr 3 (THF)...
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container_end_page | 1927 |
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container_issue | 7 |
container_start_page | 1924 |
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creator | Vasudevan, Kalyan V Smith, Nickolaus A Scott, Brian L Bennett, Bryan L Muenchausen, Ross E Gordon, John C |
description | The preparation of a series of CeBr
3
molecular adducts supported by the polydentate oxygen donor ligands diglyme, dimethoxyethane and tetraglyme is reported. The new complexes are characterized structurally by X-ray diffraction and optically by photoluminescence studies.
Dissolution of CeBr
3
(THF)
4
into polyether solutions in the presence of [BMP][NTf
2
] results in the high yielding formation of several novel polyetherate adducts of CeBr
3
. |
doi_str_mv | 10.1039/c2dt12333a |
format | Article |
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3
molecular adducts supported by the polydentate oxygen donor ligands diglyme, dimethoxyethane and tetraglyme is reported. The new complexes are characterized structurally by X-ray diffraction and optically by photoluminescence studies.
Dissolution of CeBr
3
(THF)
4
into polyether solutions in the presence of [BMP][NTf
2
] results in the high yielding formation of several novel polyetherate adducts of CeBr
3
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3
molecular adducts supported by the polydentate oxygen donor ligands diglyme, dimethoxyethane and tetraglyme is reported. The new complexes are characterized structurally by X-ray diffraction and optically by photoluminescence studies.
Dissolution of CeBr
3
(THF)
4
into polyether solutions in the presence of [BMP][NTf
2
] results in the high yielding formation of several novel polyetherate adducts of CeBr
3
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3
molecular adducts supported by the polydentate oxygen donor ligands diglyme, dimethoxyethane and tetraglyme is reported. The new complexes are characterized structurally by X-ray diffraction and optically by photoluminescence studies.
Dissolution of CeBr
3
(THF)
4
into polyether solutions in the presence of [BMP][NTf
2
] results in the high yielding formation of several novel polyetherate adducts of CeBr
3
.</abstract><doi>10.1039/c2dt12333a</doi><tpages>4</tpages></addata></record> |
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title | Ionic liquid mediated routes to polydentate oxygen-donor adducts of cerium(iii) bromideElectronic supplementary information (ESI) available: Full experimental data and X-ray data tables are provided. CCDC reference numbers 845795845798. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2dt12333a |
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