Alkaline earth imidazolate coordination polymers by solvent free melt synthesis as potential host lattices for rare earth photoluminescence: x[AE(Im)2(ImH)23], Mg, Ca, Sr, Ba, x = 12Electronic supplementary information (ESI) available. CCDC reference numbers 844009844012. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2dt12047j
The series of alkaline earth elements magnesium, calcium, strontium and barium yields single crystalline imidazolate coordination polymers by reactions of the metals with a melt of 1 H -imidazole: 1 [Mg(Im) 2 (ImH) 3 ] ( 1 ), 2 [AE(Im) 2 (ImH) 2 ], AE = Ca ( 2 ), Sr ( 3 ), and 1 [Ba(Im) 2 (ImH) 2 ]...
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