Probing the balance of attraction and repulsion in binary mixtures of dimethyl sulfoxide and n-alcoholsElectronic supplementary information (ESI) available: Additional experimental Raman and IR data as well as discussion of intermolecular interactions. See DOI: 10.1039/c2cp42902k

Probing the balance of attraction and repulsion in binary mixtures of dimethyl sulfoxide and n-alcoholsElectronic supplementary information (ESI) available: Additional experimental Raman and IR data as well as discussion of intermolecular interactions. See DOI: 10.1039/c2cp42902k

Published volumetric mixing data for DMSO- n -alcohol systems show a transition from attractive to repulsive interaction dominance for increasing alkyl chain length. A spectroscopic marker for the relative dominance of these interactions is investigated by FTIR measurements. While most vibrational m...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: Ellis, Andrew, Zehentbauer, Florian M, Kiefer, Johannes
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 196
container_issue 4
container_start_page 193
container_title
container_volume 15
creator Ellis, Andrew
Zehentbauer, Florian M
Kiefer, Johannes
description Published volumetric mixing data for DMSO- n -alcohol systems show a transition from attractive to repulsive interaction dominance for increasing alkyl chain length. A spectroscopic marker for the relative dominance of these interactions is investigated by FTIR measurements. While most vibrational modes show very similar behavior for the alcohols (C3-C5) studied, the CO torsion mode reveals a strong correlation between maximum red-shift and the balance of attraction and repulsion. The CO torsion provides a suitable spectroscopic probe for the balance of attractive and repulsive forces in DMSO-alcohol mixtures.
doi_str_mv 10.1039/c2cp42902k
format Article
fullrecord <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_c2cp42902k</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c2cp42902k</sourcerecordid><originalsourceid>FETCH-rsc_primary_c2cp42902k3</originalsourceid><addsrcrecordid>eNqFkD1PAzEMhg8EEuVjYWJBMhsMLbleKbRbBUV0ArXslZv4aMCXREkO2n_P3RXBgASTbb2v7cdOkuNUdFKRDS5lV7pedyC6b9tJK-31s_ZA3PR2vvPr_l6yH8KrECK9SrPW1smTtwttXiAuCRbIaCSBzQFj9CijtgbQKPDkSg51pQ1UfvRrKPQqlp5CbVe6oLhcM4SSc7vSipo200aWdmk5jJlk9NZoWVmcYyrIxHqKNrn1BTabzsezyQXgO2rGBdMQRkrpWkEGWjnyuulimGKBG7DJFBRGBAzwQcx1VDrIMjSwFZk2kXxhq_Ulo9-Um8NCB2ZEcPc4GcLv_x0muzlyoKOveJCc3o-fbx_aPsi5q0gq-PmPPftfP_tLnzuVZ59N05Nx</addsrcrecordid><sourcetype>Enrichment Source</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Probing the balance of attraction and repulsion in binary mixtures of dimethyl sulfoxide and n-alcoholsElectronic supplementary information (ESI) available: Additional experimental Raman and IR data as well as discussion of intermolecular interactions. See DOI: 10.1039/c2cp42902k</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Ellis, Andrew ; Zehentbauer, Florian M ; Kiefer, Johannes</creator><creatorcontrib>Ellis, Andrew ; Zehentbauer, Florian M ; Kiefer, Johannes</creatorcontrib><description>Published volumetric mixing data for DMSO- n -alcohol systems show a transition from attractive to repulsive interaction dominance for increasing alkyl chain length. A spectroscopic marker for the relative dominance of these interactions is investigated by FTIR measurements. While most vibrational modes show very similar behavior for the alcohols (C3-C5) studied, the CO torsion mode reveals a strong correlation between maximum red-shift and the balance of attraction and repulsion. The CO torsion provides a suitable spectroscopic probe for the balance of attractive and repulsive forces in DMSO-alcohol mixtures.</description><identifier>ISSN: 1463-9076</identifier><identifier>EISSN: 1463-9084</identifier><identifier>DOI: 10.1039/c2cp42902k</identifier><language>eng</language><creationdate>2012-12</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Ellis, Andrew</creatorcontrib><creatorcontrib>Zehentbauer, Florian M</creatorcontrib><creatorcontrib>Kiefer, Johannes</creatorcontrib><title>Probing the balance of attraction and repulsion in binary mixtures of dimethyl sulfoxide and n-alcoholsElectronic supplementary information (ESI) available: Additional experimental Raman and IR data as well as discussion of intermolecular interactions. See DOI: 10.1039/c2cp42902k</title><description>Published volumetric mixing data for DMSO- n -alcohol systems show a transition from attractive to repulsive interaction dominance for increasing alkyl chain length. A spectroscopic marker for the relative dominance of these interactions is investigated by FTIR measurements. While most vibrational modes show very similar behavior for the alcohols (C3-C5) studied, the CO torsion mode reveals a strong correlation between maximum red-shift and the balance of attraction and repulsion. The CO torsion provides a suitable spectroscopic probe for the balance of attractive and repulsive forces in DMSO-alcohol mixtures.</description><issn>1463-9076</issn><issn>1463-9084</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFkD1PAzEMhg8EEuVjYWJBMhsMLbleKbRbBUV0ArXslZv4aMCXREkO2n_P3RXBgASTbb2v7cdOkuNUdFKRDS5lV7pedyC6b9tJK-31s_ZA3PR2vvPr_l6yH8KrECK9SrPW1smTtwttXiAuCRbIaCSBzQFj9CijtgbQKPDkSg51pQ1UfvRrKPQqlp5CbVe6oLhcM4SSc7vSipo200aWdmk5jJlk9NZoWVmcYyrIxHqKNrn1BTabzsezyQXgO2rGBdMQRkrpWkEGWjnyuulimGKBG7DJFBRGBAzwQcx1VDrIMjSwFZk2kXxhq_Ulo9-Um8NCB2ZEcPc4GcLv_x0muzlyoKOveJCc3o-fbx_aPsi5q0gq-PmPPftfP_tLnzuVZ59N05Nx</recordid><startdate>20121219</startdate><enddate>20121219</enddate><creator>Ellis, Andrew</creator><creator>Zehentbauer, Florian M</creator><creator>Kiefer, Johannes</creator><scope/></search><sort><creationdate>20121219</creationdate><title>Probing the balance of attraction and repulsion in binary mixtures of dimethyl sulfoxide and n-alcoholsElectronic supplementary information (ESI) available: Additional experimental Raman and IR data as well as discussion of intermolecular interactions. See DOI: 10.1039/c2cp42902k</title><author>Ellis, Andrew ; Zehentbauer, Florian M ; Kiefer, Johannes</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c2cp42902k3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ellis, Andrew</creatorcontrib><creatorcontrib>Zehentbauer, Florian M</creatorcontrib><creatorcontrib>Kiefer, Johannes</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ellis, Andrew</au><au>Zehentbauer, Florian M</au><au>Kiefer, Johannes</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Probing the balance of attraction and repulsion in binary mixtures of dimethyl sulfoxide and n-alcoholsElectronic supplementary information (ESI) available: Additional experimental Raman and IR data as well as discussion of intermolecular interactions. See DOI: 10.1039/c2cp42902k</atitle><date>2012-12-19</date><risdate>2012</risdate><volume>15</volume><issue>4</issue><spage>193</spage><epage>196</epage><pages>193-196</pages><issn>1463-9076</issn><eissn>1463-9084</eissn><abstract>Published volumetric mixing data for DMSO- n -alcohol systems show a transition from attractive to repulsive interaction dominance for increasing alkyl chain length. A spectroscopic marker for the relative dominance of these interactions is investigated by FTIR measurements. While most vibrational modes show very similar behavior for the alcohols (C3-C5) studied, the CO torsion mode reveals a strong correlation between maximum red-shift and the balance of attraction and repulsion. The CO torsion provides a suitable spectroscopic probe for the balance of attractive and repulsive forces in DMSO-alcohol mixtures.</abstract><doi>10.1039/c2cp42902k</doi><tpages>4</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1463-9076
ispartof
issn 1463-9076
1463-9084
language eng
recordid cdi_rsc_primary_c2cp42902k
source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
title Probing the balance of attraction and repulsion in binary mixtures of dimethyl sulfoxide and n-alcoholsElectronic supplementary information (ESI) available: Additional experimental Raman and IR data as well as discussion of intermolecular interactions. See DOI: 10.1039/c2cp42902k
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-09T01%3A52%3A11IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-rsc&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Probing%20the%20balance%20of%20attraction%20and%20repulsion%20in%20binary%20mixtures%20of%20dimethyl%20sulfoxide%20and%20n-alcoholsElectronic%20supplementary%20information%20(ESI)%20available:%20Additional%20experimental%20Raman%20and%20IR%20data%20as%20well%20as%20discussion%20of%20intermolecular%20interactions.%20See%20DOI:%2010.1039/c2cp42902k&rft.au=Ellis,%20Andrew&rft.date=2012-12-19&rft.volume=15&rft.issue=4&rft.spage=193&rft.epage=196&rft.pages=193-196&rft.issn=1463-9076&rft.eissn=1463-9084&rft_id=info:doi/10.1039/c2cp42902k&rft_dat=%3Crsc%3Ec2cp42902k%3C/rsc%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true