Direct measurement of Criegee intermediate (CH2OO) reactions with acetone, acetaldehyde, and hexafluoroacetone

Criegee biradicals, i.e. , carbonyl oxides, are critical intermediates in ozonolysis and have been implicated in autoignition chemistry and other hydrocarbon oxidation systems, but until recently the direct measurement of their gas-phase kinetics has not been feasible. Indirect determinations of Cri...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2012-08, Vol.14 (3), p.1391-14
Hauptverfasser:	Taatjes, Craig A, Welz, Oliver, Eskola, Arkke J, Savee, John D, Osborn, David L, Lee, Edmond P. F, Dyke, John M, Mok, Daniel W. K, Shallcross, Dudley E, Percival, Carl J
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology General and physical chemistry Photochemistry Physical chemistry of induced reactions (with radiations, particles and ultrasonics)
Online-Zugang:	Volltext
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