Gas-phase lanthanide chloride clusters: relationships among ESI abundances and DFT structures and energeticsElectronic supplementary information (ESI) available: Mass spectra of LnCl3 (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu), LnBr3 (Ln = La, Ce, Pr, Nd, Sm, Lu), and LnI3 (Ln = La, Lu). Mass spectra of diluted LaCl3 and LuCl3 solutions, and of solutions with an excess of chloride. Geometrical structures of high-energy isomers of La2Cl7 and Lu2Cl7, different views of La6Cl19,

Gas-phase lanthanide chloride clusters: relationships among ESI abundances and DFT structures and energeticsElectronic supplementary information (ESI) available: Mass spectra of LnCl3 (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu), LnBr3 (Ln = La, Ce, Pr, Nd, Sm, Lu), and LnI3 (Ln = La, Lu). Mass spectra of diluted LaCl3 and LuCl3 solutions, and of solutions with an excess of chloride. Geometrical structures of high-energy isomers of La2Cl7 and Lu2Cl7, different views of La6Cl19,

Anionic lanthanide chloride clusters, Ln n Cl 3 n +1 , were produced by electrospray ionization (ESI) of LnCl 3 in isopropanol, where Ln = LaLu (except Pm); the clusters were characterized using a quadrupole ion trap mass spectrometer. High-abundance magic number clusters were apparent at n = 4 for...

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Hauptverfasser: Rutkowski, Philip X, Michelini, Maria C, Gibson, John K
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Sprache:eng
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