Phase formation in the BaB2O4-BaF2-BaO system and new non-centrosymmetric solid-solution series Ba7(BO3)4−xF2+3xCCDC 891832. For crystallographic data in CIF or other electronic format see DOI: 10.1039/c2ce26122g
Detailed study of the BaB 2 O 4 -BaF 2 -BaO system resulted in the discovery of the new Ba 7 (BO 3 ) 4− x F 2+3 x solid solution belonging to the BaF 2 -Ba 3 (BO 3 ) 2 section. The distinguishing feature of the crystal structure of Ba 7 (BO 3 ) 4− x F 2+3 x phase is its extensive (BO 3 ) 3− ↔ 3F − a...
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