Rhodium(iii)-catalyzed allylic C-H bond amination. Synthesis of cyclic amines from ω-unsaturated N-sulfonylaminesElectronic supplementary information (ESI) available. See DOI: 10.1039/c2cc36067e
For the first time, intramolecular allylic amination was conducted using rhodium( iii ) according to an "inner-sphere" type mechanism with amines activated by only one electron-withdrawing group. The activation of C(sp 3 )-H bonds was chemoselective and allows the access to a variety of su...
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| creator | Cochet, Thomas Bellosta, Véronique Roche, Didier Ortholand, Jean-Yves Greiner, Alfred Cossy, Janine |
| description | For the first time, intramolecular allylic amination was conducted using rhodium(
iii
) according to an "inner-sphere" type mechanism with amines activated by only one electron-withdrawing group. The activation of C(sp
3
)-H bonds was chemoselective and allows the access to a variety of substituted cyclic amines such as pyrrolidines and piperidines.
For the first time, intramolecular allylic amination was conducted using rhodium(
iii
) according to an "inner-sphere" type mechanism with amines activated by only one electron-withdrawing group. |
| doi_str_mv | 10.1039/c2cc36067e |
| format | Article |
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iii
) according to an "inner-sphere" type mechanism with amines activated by only one electron-withdrawing group. The activation of C(sp
3
)-H bonds was chemoselective and allows the access to a variety of substituted cyclic amines such as pyrrolidines and piperidines.
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iii
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iii
) according to an "inner-sphere" type mechanism with amines activated by only one electron-withdrawing group. The activation of C(sp
3
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iii
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iii
) according to an "inner-sphere" type mechanism with amines activated by only one electron-withdrawing group. The activation of C(sp
3
)-H bonds was chemoselective and allows the access to a variety of substituted cyclic amines such as pyrrolidines and piperidines.
For the first time, intramolecular allylic amination was conducted using rhodium(
iii
) according to an "inner-sphere" type mechanism with amines activated by only one electron-withdrawing group.</abstract><doi>10.1039/c2cc36067e</doi><tpages>3</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Rhodium(iii)-catalyzed allylic C-H bond amination. Synthesis of cyclic amines from ω-unsaturated N-sulfonylaminesElectronic supplementary information (ESI) available. See DOI: 10.1039/c2cc36067e |
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