A 32 vertex polyhedron via supramolecular assembly of silanedithiolate silanolate unitsElectronic supplementary information (ESI) available: Details of the synthesis, crystallographic data for 4 and detailed tables with geometric parameters, Tables S1-S4, Fig. S1 and S2. See DOI: 10.1039/c2cc33883a
A high yield synthesis of the first silanedithiolate silanolate is reported which spontaneously assembles forming an inorganic rugby ball shaped 32 vertex polyhedral cluster stabilized by sterically demanding 2,6-dimesitylphenyl substituents and two LiCl units. A silanedithiolate silanolate assemble...
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creator | Spirk, Stefan Belaj, Ferdinand Hurkes, Natascha Pietschnig, Rudolf |
description | A high yield synthesis of the first silanedithiolate silanolate is reported which spontaneously assembles forming an inorganic rugby ball shaped 32 vertex polyhedral cluster stabilized by sterically demanding 2,6-dimesitylphenyl substituents and two LiCl units.
A silanedithiolate silanolate assembles spontaneously forming an inorganic rugby ball shaped 32 vertex polyhedral cluster stabilized by organic substituents and LiCl. |
doi_str_mv | 10.1039/c2cc33883a |
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title | A 32 vertex polyhedron via supramolecular assembly of silanedithiolate silanolate unitsElectronic supplementary information (ESI) available: Details of the synthesis, crystallographic data for 4 and detailed tables with geometric parameters, Tables S1-S4, Fig. S1 and S2. See DOI: 10.1039/c2cc33883a |
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