Generation of diamondoid hydrocarbons as confined compounds in SAPO-34 catalyst in the conversion of methanolElectronic supplementary information (ESI) available: Experimental section, catalytic performances, confined organics determination, reactivity of confined adamantanes and aromatics and the retained compounds in SAPO-34, 18 and 35 after methanol conversion. See DOI: 10.1039/c2cc17676a

Generation of diamondoid hydrocarbons as confined compounds in SAPO-34 catalyst in the conversion of methanolElectronic supplementary information (ESI) available: Experimental section, catalytic performances, confined organics determination, reactivity of confined adamantanes and aromatics and the retained compounds in SAPO-34, 18 and 35 after methanol conversion. See DOI: 10.1039/c2cc17676a

Formation of adamantane hydrocarbons and their confinement in SAPO-34 caused the long induction period and the quick catalyst deactivation in methanol conversion. Via ship-in-a-bottle synthesis, adamantane and methyladamantanes could be produced from methanol conversion in the cage of 8-ring SAPO ca...

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Hauptverfasser: Wei, Yingxu, Li, Jinzhe, Yuan, Cuiyu, Xu, Shutao, Zhou, You, Chen, Jingrun, Wang, Quanyi, Zhang, Qing, Liu, Zhongmin
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container_volume 48
creator Wei, Yingxu
Li, Jinzhe
Yuan, Cuiyu
Xu, Shutao
Zhou, You
Chen, Jingrun
Wang, Quanyi
Zhang, Qing
Liu, Zhongmin
description Formation of adamantane hydrocarbons and their confinement in SAPO-34 caused the long induction period and the quick catalyst deactivation in methanol conversion. Via ship-in-a-bottle synthesis, adamantane and methyladamantanes could be produced from methanol conversion in the cage of 8-ring SAPO catalysts under very mild reaction conditions. The generation of diamondoid hydrocarbons in SAPO-34 as a new kind of coke species interpreted the quick deactivation of methanol conversion.
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title Generation of diamondoid hydrocarbons as confined compounds in SAPO-34 catalyst in the conversion of methanolElectronic supplementary information (ESI) available: Experimental section, catalytic performances, confined organics determination, reactivity of confined adamantanes and aromatics and the retained compounds in SAPO-34, 18 and 35 after methanol conversion. See DOI: 10.1039/c2cc17676a
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