Click-modification of a functionalized poly(3,4-ethylenedioxythiophene) (PEDOT) soluble in organic solventsElectronic supplementary information (ESI) available: Chemicals, IR-spectra, and CV. See DOI: 10.1039/c2cc17374c

Click-modification of a functionalized poly(3,4-ethylenedioxythiophene) (PEDOT) soluble in organic solventsElectronic supplementary information (ESI) available: Chemicals, IR-spectra, and CV. See DOI: 10.1039/c2cc17374c

A PEDOT-based conductive copolymer soluble in organic solvents was synthesized electrochemically using dihexyl-EDOT and azidomethyl-EDOT as monomers and was successfully post-functionalized by click-cycloaddition reaction with a functionalized terminal alkyne under mild heterogeneous conditions. For...

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Hauptverfasser: Bu, Hang-Beom, Gtz, Gnther, Reinold, Egon, Vogt, Astrid, Azumi, Reiko, Segura, Jos L, Buerle, Peter
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creator Bu, Hang-Beom
Gtz, Gnther
Reinold, Egon
Vogt, Astrid
Azumi, Reiko
Segura, Jos L
Buerle, Peter
description A PEDOT-based conductive copolymer soluble in organic solvents was synthesized electrochemically using dihexyl-EDOT and azidomethyl-EDOT as monomers and was successfully post-functionalized by click-cycloaddition reaction with a functionalized terminal alkyne under mild heterogeneous conditions. Formation of a PEDOT copolymer soluble in organic solvents has been achieved by electrochemical copolymerization of monomers. In a post-functionalization step, facile immobilization of electron-accepting phthalimide was achieved by click-reaction with high conversion efficiencies.
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title Click-modification of a functionalized poly(3,4-ethylenedioxythiophene) (PEDOT) soluble in organic solventsElectronic supplementary information (ESI) available: Chemicals, IR-spectra, and CV. See DOI: 10.1039/c2cc17374c
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