Building large supramolecular nanocapsules with europium cationsElectronic supplementary information (ESI) available: Detailed synthetic procedures, instrumentations, NMR titration spectra, ESMS spectrum of the [Eu4L34]12+ solution, the molecular structure of [Eu4L34]12+ and the crystal packing, 35Cl NMR spectrum, 1H NMR for the exchange with BF4. See DOI: 10.1039/c2cc17322k

Building large supramolecular nanocapsules with europium cationsElectronic supplementary information (ESI) available: Detailed synthetic procedures, instrumentations, NMR titration spectra, ESMS spectrum of the [Eu4L34]12+ solution, the molecular structure of [Eu4L34]12+ and the crystal packing, 35Cl NMR spectrum, 1H NMR for the exchange with BF4. See DOI: 10.1039/c2cc17322k

A new tripodal ligand has been designed by connecting pyridine-based coordination units to a rigid triptycene moiety. Its reaction with europium( iii ) provides three-dimensional tetranuclear edifices, whose structural and photophysical characteristics as well as hostguest interactions are discussed...

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Hauptverfasser: Hamacek, Josef, Poggiali, Daniele, Zebret, Soumaila, Aroussi, Badr El, Schneider, Markus W, Mastalerz, Michael
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creator Hamacek, Josef
Poggiali, Daniele
Zebret, Soumaila
Aroussi, Badr El
Schneider, Markus W
Mastalerz, Michael
description A new tripodal ligand has been designed by connecting pyridine-based coordination units to a rigid triptycene moiety. Its reaction with europium( iii ) provides three-dimensional tetranuclear edifices, whose structural and photophysical characteristics as well as hostguest interactions are discussed in this contribution. New tetranuclear triptycene-derived complexes allow sensitising the Eu III luminescence in near-UV and possess a large internal cavity for guest accommodation.
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title Building large supramolecular nanocapsules with europium cationsElectronic supplementary information (ESI) available: Detailed synthetic procedures, instrumentations, NMR titration spectra, ESMS spectrum of the [Eu4L34]12+ solution, the molecular structure of [Eu4L34]12+ and the crystal packing, 35Cl NMR spectrum, 1H NMR for the exchange with BF4. See DOI: 10.1039/c2cc17322k
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