Kinetics of Zn2+ complexation by a ditopic phenanthroline-azamacrocyclic scorpiand-like receptorElectronic supplementary information (ESI) available. See DOI: 10.1039/c2cc16831f

Coordination of Zn 2+ to a ditopic phenanthroline-macrocycle receptor takes place in three steps, the first one being the coordination to the phenanthroline, followed by the slow movement of the metal to the polyamine macrocycle and a final re-arrangement to coordinate the pendent arm. Coordination...

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Hauptverfasser: Gonzalez, Jorge, Gavara, Raquel, Gadea, Oscar, Blasco, Salvador, Garca-Espaa, Enrique, Pina, Fernando
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container_end_page 1996
container_issue 14
container_start_page 1994
container_title
container_volume 48
creator Gonzalez, Jorge
Gavara, Raquel
Gadea, Oscar
Blasco, Salvador
Garca-Espaa, Enrique
Pina, Fernando
description Coordination of Zn 2+ to a ditopic phenanthroline-macrocycle receptor takes place in three steps, the first one being the coordination to the phenanthroline, followed by the slow movement of the metal to the polyamine macrocycle and a final re-arrangement to coordinate the pendent arm. Coordination of Zn 2+ to a ditopic aza-scorpiand macrocycle with a pendent phenanthroline unit occurs in the first place at the phenanthroline site, followed by the slow movement of the metal to the polyamine macrocycle and a final re-arrangement to coordinate the pendent arm.
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title Kinetics of Zn2+ complexation by a ditopic phenanthroline-azamacrocyclic scorpiand-like receptorElectronic supplementary information (ESI) available. See DOI: 10.1039/c2cc16831f
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