A unique proton coupled electron transfer pathway for electrochemical reduction of acetophenone in the ionic liquid [BMIM][BF4] under a carbon dioxide atmosphere

The mechanism of electrochemical reduction of acetophenone in 1-butyl-3-methylimidazolium tetrafluroborate ([BMIM][BF 4 ]) under nitrogen (N 2 ) and carbon dioxide (CO 2 ) atmospheres have been investigated using transient voltammetry, steady-state voltammetry, bulk electrolysis and numerical simula...

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Veröffentlicht in:	Green chemistry : an international journal and green chemistry resource : GC 2011-01, Vol.13 (12), p.3461-3468
Hauptverfasser:	Zhao, Shu-Feng, Wu, La-Xia, Wang, Huan, Lu, Jia-Xing, Bond, Alan M, Zhang, Jie
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions Chemistry Electrochemistry Exact sciences and technology General and physical chemistry Heterocyclic compounds Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings Kinetics and mechanisms Noncondensed benzenic compounds Organic chemistry Preparations and properties Reactivity and mechanisms
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